Silver Nanoclusters and Rare-earth Ions Co-doped Luminescent Glasses

被引:0
|
作者
Yu J. [1 ]
Ye S. [1 ]
Xv X. [1 ]
Wang D. [1 ]
机构
[1] School of Materials Science and Engineering, Tongji University, Shanghai
关键词
Energy transfer; Glass; Rare earth ions; Silver nanoclusters;
D O I
10.14062/j.issn.0454-5648.20210033
中图分类号
学科分类号
摘要
Silver nanoclusters (Ag-NCs) with a small number of silver atoms or ions have discrete energy bands, thus exhibiting a size-dependent tunable emitting behavior with a high quantum yield. The Ag-NCs can be used as desirable sensitizers for rare-earth element ions to achieve an enhanced and tunable emission for diverse applications. Glasses are desirable matrixes to disperse and stabilize Ag-NCs due to their high transparency and excellent chemical/thermal stability. This review represented the preparation and control of Ag-NCs dispersed glasses, the luminescent properties of Ag-NCs and their sensitization for rare-earth element ions as well. The applications of Ag-NCs and rare-earth element ions co-doped glasses in a white and tunable light emission and solar cells were described. Besides, the problems encountered in current studies and the corresponding possible solutions were also discussed. © 2021, Editorial Department of Journal of the Chinese Ceramic Society. All right reserved.
引用
收藏
页码:1519 / 1526
页数:7
相关论文
共 53 条
  • [1] KREIBIG U, VOLLMER M., Optical Properties of Metal Clusters, (1995)
  • [2] COUTINO-GONZALEZ E, BAEKELANT W, STEELE J A, Et al., Silver clusters in zeolites: From self-assembly to ground-breaking luminescent properties, Accounts Chem Res, 50, pp. 2353-2361, (2017)
  • [3] DIEZ I, RAS R H, Fluorescent silver nanoclusters, Nanoscale, 3, pp. 1963-1970, (2011)
  • [4] KUZNETSOV A S, VELAZQUEZ J J, TIKHOMIROV V K, Et al., Quantum yield of luminescence of Ag nanoclusters dispersed within transparent bulk glass vs. glass composition and temperature, Appl Phys Lett, 101, (2012)
  • [5] CUONG N T, TIKHOMIROV V K, CHIBOTARU L F, Et al., Experiment and theoretical modeling of the luminescence of silver nanoclusters dispersed in oxyfluoride glass, J Chem Phys, 136, (2012)
  • [6] SHESTAKOV M V, CUONG N T, TIKHOMIROV V K, Et al., Quantum chemistry modeling of luminescence kinetics of Ag nanoclusters dispersed in glass host, J Phys Chem C, 117, pp. 7796-7800, (2013)
  • [7] GRANDJEAN D, COUTINO-GONZALEZ E, CUONG N T, Et al., Origin of the bright photoluminescence of few-atom silver clusters confined in LTA zeolites, Science, 361, pp. 686-690, (2018)
  • [8] XU X, ZHAO J, LUO X, Et al., Stabilization of fluorescent [Ag<sub>m</sub>]<sup>n+</sup> quantum clusters in multiphase inorganic glass-ceramics for white LEDs, ACS Appl Nano Mater, 2, pp. 2854-2863, (2019)
  • [9] KUZNETSOV A S, TIKHOMIROV V K, SHESTAKOV M V, Et al., Ag nanocluster functionalized glasses for efficient photonic conversion in light sources, solar cells and flexible screen monitors, Nanoscale, 5, pp. 10065-10075, (2013)
  • [10] GONELLA F., Silver doping of glasses, Ceram Int, 41, pp. 6693-6701, (2015)