Tribological Behavior under Wide Temperature Range Cyclic Conditions and Regeneration Mechanism of High and Low Temperature Lubricating Phase of NiAl-Bi2O3 Coating after Heat Treatment

被引：0
作者：
Sun H. [1 ,2 ]
Yang J. [1 ,2 ]
Yi G. [1 ,2 ]
Wan S. [1 ,2 ]
Wang W. [1 ]
Shan Y. [1 ]
Bai L. [1 ,2 ]
机构：
[1] State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Gansu, Lanzhou
[2] Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing
来源：
Mocaxue Xuebao/Tribology | 2023年 / 43卷 / 01期
基金：
中国国家自然科学基金;
关键词：
adaptive regeneration; atmospheric plasma spraying (APS); Bi[!sub]2[!/sub]O[!sub]3[!/sub; coating; heat treatment; NiBi; tribological properties;
D O I：
10.16078/j.tribology.2022052
中图分类号：
学科分类号：
摘要：
The plasma sprayed NiAl-Bi2O3 composite coating was heat treated under the condition of argon atmosphere of 800 °C. Then, the friction and wear properties of the resulting heat treated NiAl-Bi2O3 composite coating in the temperature range from room temperature to 800 °C were evaluated by UMT-3 high temperature friction tester. By analyzing the evolution of composition and microstructure of NiAl-Bi2O3 composite coating before and after heat treatment, and deeply exploring the frictional surface/interface during the process of friction test at different temperatures, the adaptive regeneration mechanism of high and low temperature lubricating phases (NiBi, Bi2O3 and NiO) within the heat-treated NiAl-Bi2O3 coating was studied for the first time. Meanwhile, the tribological behavior of the heat-treated NiAl-Bi2O3 coating under temperature cycle test conditions of wide temperature range was analyzed in depth. The experimental results showed that the condition of heat treatment of 800 °C under argon atmosphere was able to promote the formation of dispersion-enhanced Al2O3 phase and intermetallic compound NiBi phase within the heat-treated NiAl-Bi2O3 composite coating. It was proved that the intermetallic compound NiBi had medium and low temperature lubricity in this study. At the same time, NiAl-Bi2O3 composite coating produced a significant reduction in friction and wear from room temperature to 800 °C through the heat treatment process. Especially when test temperature reached 400 °C, the friction coefficient and wear rate had a dramatic reduction, where the friction coefficient was reduced from 0.39 before heat treatment to 0.28 after heat treatment, and the wear rate was reduced by a full order of magnitude [from 35.56×10−5 mm3/(N·m) before heat treatment to 8.53 × 10−5 mm3/(N·m) after heat treatment]. When the test temperature rose to 800 °C, the contact surface of the heat-treated coating generated high-temperature lubricating phase (Bi2O3 and NiO) again through the high-temperature friction oxidation. And then solid lubricants (Bi2O3 and NiO) and reinforced phase Al2O3 adaptively formed a continuous lubricating tribo-layer on the worn surface during the sliding process, and this played a significant synergistic lubrication and anti-wear role. As a result, the lubricating performance and wear resistance capability of the heat-treated NiAl-Bi2O3 coating under the conditions of wide temperature range and high and low temperature cycle condition were significantly improved. It could be concluded that after the heat treatment, there was a mechanism of lubricating phase regeneration and continuous tribo-layer formation on the worn surface of NiAl-Bi2O3 composite coating during the friction process. This mechanism was expected to further improve the service life of metal matrix composite coatings in a wide temperature range. This study had important practical significance for the development of new technologies of solid lubrication and anti-wear materials. © 2023 Science Press. All rights reserved.
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页码：49 / 63
页数：14
相关论文
共 24 条
  • [1] Sun Huwei, Yi Gewen, Wan Shanhong, Et al., Effect of adding soft Bi<sub>2</sub>O<sub>3</sub> on structural modification and tribological regulation of Ni-5 wt% Al composite coating in wide temperatures range, Surface and Coatings Technology, 405, (2021)
  • [2] Wang Xinpeng, Yi Gewen, Jia Junhong, Et al., Preparation and tribological properties of NiAl-TiO<sub>2</sub>/Bi<sub>2</sub>O<sub>3</sub> nanocomposite coatings in wide temperature range, Tribology, 38, 5, pp. 570-576, (2018)
  • [3] Sun Huwei, Wan Shanhong, Yi Gewen, Et al., Friction and wear behaviors of NiAl-Bi<sub>2</sub>O<sub>3</sub>-Ag-Cr<sub>2</sub>O<sub>3</sub> composite coating in the thermal cycle of RT-800 °C, Tribology International, 159, (2021)
  • [4] Sun Huwei, Yi Gewen, Wan Shanhong, Et al., Effect of Cr<sub>2</sub>O<sub>3</sub> addition on mechanical and tribological properties of atmospheric plasma-sprayed NiAl-Bi<sub>2</sub>O<sub>3</sub> composite coatings, Surface and Coatings Technology, 427, (2021)
  • [5] Kato H, Komai K., Tribofilm formation and mild wear by tribosintering of nanometer-sized oxide particles on rubbing steel surfaces[J], Wear, 262, 1–2, pp. 36-41, (2007)
  • [6] Chen Jianmin, Lu Xiaowei, Li Hongxuan, Et al., Progress of solid self-lubricating coating over a wide range of temperature, Tribology, 34, 5, pp. 592-600, (2014)
  • [7] Fan Xiangjuan, Li Wensheng, Yang Jun, Et al., Tribological behaviors of Ni<sub>3</sub>Al-based coating coupled with different counterpart materials in wide temperature range, Tribology, 40, 6, pp. 687-696, (2020)
  • [8] Shi Peiying, Yi Gewen, Wang Qihua, Et al., Tribological properties of nickel-based composite coatings with the addition of MoO<sub>3</sub>ZnO, Tribology, 41, 6, pp. 936-945, (2021)
  • [9] Lu Xiaolong, Liu Xiubo, Yu Pengcheng, Et al., Effects of post heat-treatment on microstructure and tribological properties of Ni60/HBN self-lubricating anti-wear composite coating on 304 stainless steel by laser cladding, Tribology, 36, 1, pp. 48-54, (2016)
  • [10] E Jisheng, Zhang Jun, Ma Chao, Et al., The influence of heat treatment and microstructure of glass-ceramics coating on tribological properties, Tribology, 12, 3, pp. 233-239, (1992)
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