Recent progress and perspectives of metal organic frameworks (MOFs) for the detection of food contaminants

被引：14

作者：

Manoj D. ^{[1
]}

Rajendran S. ^{[1
,2
,3
]}

Murphy M. ^{[4
]}

Jalil A.A. ^{[5
,6
]}

Sonne C. ^{[7
]}

机构：

[1] Departamento de Ingeniería Mecánica, Facultad de Ingeniería, Universidad de Tarapacá, Avda. General Velásquez 1775, Arica

[2] Department of Chemical Engineering, Lebanese American University, Byblos

[3] University Centre for Research & Development, Department of Mechanical Engineering, Chandigarh University, Punjab, Mohali

[4] Department of Chemistry, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences (SIMATS), Tamil Nadu, Chennai

[5] Centre of Hydrogen Energy, Institute of Future Energy, UTM Johor Bahru, Johor

[6] Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTM Johor Bahru, Johor

[7] Department of Ecoscience, Arctic Research Centre (ARC), Aarhus University, Frederiksborgvej 399, PO Box 358, Roskilde

来源：

Chemosphere | 2023年 / 340卷

关键词：

Electrochemical detection; Food contaminants; Heavy metals; Metal-organic framework; Modified electrode;

D O I：

10.1016/j.chemosphere.2023.139820

中图分类号：

学科分类号：

摘要：

Over the past decades, increasing research in metal-organic frameworks (MOFs) being a large family of highly tunable porous materials with intrinsic physical properties, show propitious results for a wide range of applications in adsorption, separation, electrocatalysis, and electrochemical sensors. MOFs have received substantial attention in electrochemical sensors owing to their large surface area, active metal sites, high chemical and thermal stability, and tunable structure with adjustable pore diameters. Benefiting from the superior properties, MOFs and MOF-derived carbon materials act as promising electrode material for the detection of food contaminants. Although several reviews have been reported based on MOF and its nanocomposites for the detection of food contaminants using various analytical methods such as spectrometric, chromatographic, and capillary electrophoresis. But there no significant review has been devoted to MOF/and its derived carbon-based electrodes using electrochemical detection of food contaminants. Here we review and classify MOF-based electrodes over the period between 2017 and 2022, concerning synthetic procedures, electrode fabrication process, and the possible mechanism for detection of the food contaminants which include: heavy metals, antibiotics, mycotoxins, and pesticide residues. The merits and demerits of MOF as electrode material and the need for the fabrication of MOF and its composites/derivatives for the determination of food contaminants are discussed in detail. At last, the current opportunities, key challenges, and prospects in MOF for the development of smart sensing devices for future research in this field are envisioned. © 2023 Elsevier Ltd

引用

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