Direct conversion of CO2 to light aromatics by composite ZrCr-C/ZSM-5 catalyst

被引:13
作者
Shi, Ying [1 ]
Gao, Weizhe [1 ]
Wang, Kangzhou [2 ]
Zhang, Lijun [1 ]
Feng, Haozhe [1 ]
Guo, Xiaoyu [1 ]
He, Yingluo [1 ]
Feng, Xiaobo [3 ]
Liu, Qiang [4 ]
Li, Tao [4 ]
Pan, Yufeng [4 ]
Ma, Qingxiang [5 ]
Tsubaki, Noritatsu [1 ]
机构
[1] Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan
[2] Ningxia Univ, Sch Mat & New Energy, Yinchuan 750021, Ningxia, Peoples R China
[3] China Univ Min & Technol, Jiangsu Prov Engn Res Ctr Fine Utilizat Carbon Re, Xuzhou 221116, Jiangsu, Peoples R China
[4] Coal Gasificat & Coal Based Adv Mat Shandong Ener, Natl Engn Res Ctr, Jinan 250014, Peoples R China
[5] Ningxia Univ, Coll Chem & Chem Engn, State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Ningxia, Peoples R China
来源
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY | 2024年 / 353卷
基金
日本学术振兴会;
关键词
CO2; hydrogenation; Tandem reaction; Light aromatics; Oxide-zeolite catalyst; Carbon modified zeolite; SELECTIVE CONVERSION; PARA-XYLENE; CARBON-DIOXIDE; SYNGAS; METHANOL; OLEFINS; HZSM-5; HYDROGENATION; BENZENE;
D O I
10.1016/j.apcatb.2024.124068
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In recent years, the direct and efficient conversion of CO2 to light aromatics (BTX: benzene, toluene and xylene) has attracted wide attention. It not only reduces the CO2 concentration in the atmosphere but also provides a promising non-petroleum technology to produce BTX. Herein, a composite ZrCr-C/ZSM-5 catalyst was developed for CO2 to BTX. Different with conventional SiO2 modification method, the HZSM-5 zeolite was modified by amorphous carbon (C) through a facile modified impregnation method. The amorphous C could enter the internal channel of HZSM-5 zeolite and poison partial acid sites. In CO2 to BTX reaction, after introducing 1.45 wt % C on HZSM-5 zeolite, BTX selectivity increased from 36.2% to 45.4%. In addition, the ZrCr-1.45 C/ZSM-5 catalyst exhibited 46.9% BTX selectivity with 13.5% CO2 conversion, under 5.0 MPa, 360 degrees C and 4800 mL/g(cat)/h. This work not only paves a new strategy to modify HZSM-5 zeolite but also provides an efficient composite catalyst for direct conversion of CO2 to BTX.
引用
收藏
页数:8
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