Corrosion inhibition of galvanized steel by cobalt(II) nitrate

被引:0
作者
Thai T.T. [1 ]
Trinh A.T. [1 ,2 ]
Tam Pham T.T. [3 ]
Nguyen X.H. [3 ]
Pham G.V. [1 ]
Hang To T.X. [1 ,2 ]
机构
[1] Institute for Tropical Technology, Vietnam Academy of Science and Technology, A13 Building, 18 Hoang Quoc Viet, Cau Giay, Hanoi
[2] Graduate University of Science and Technology, Vietnam Academy of Science and Technoloy, 18 Hoang Quoc Viet, Cau Giay, Hanoi
[3] Faculty of Chemistry, VNU University of Science, Vietnam National University, 19 Le Thanh Tong, Hanoi
关键词
Cobalt; EIS; Galvanized steel; Inhibitor; Polarization;
D O I
10.1380/EJSSNT.2021.48
中图分类号
学科分类号
摘要
This study presents the inhibitive property of Co(II) ions in the corrosion protection of commercial hot-dip galvanized steel in aggressive solution. The polarization measurements reveal the action of Co(II) cations in the anodic branch with the inhibitive efficiency determined at 96% for 0.01 M of Co(II). The corrosion resistance was reinforced by a passive layer formed at Zn surface, that was assessed by the electrochemical measurements. The existence and the crystal structure of this protective layer was analyzed by field-emission scanning electron microscopy observations. X-ray diffraction analysis was confirmed the formation of zinc cobalt hydroxide and cobalt zinc oxide on the Zn surface that attributed to the inhibitive action of the Co cations. © 2021 The Japan Society of Vacuum and Surface Science. All rights reserved.
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页码:48 / 54
页数:6
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