Effects of microstructure and alloy composition on hydroxyapatite precipitation on alkaline treated α/β titanium alloys

被引:22
作者
Abdel-Salam M. [1 ]
El-Hadad S. [2 ]
Khalifa W. [1 ]
机构
[1] Cairo University, Faculty of Engineering, Dept. Mining, Petroleum and Metallurgical, Engineering, Giza
[2] Central Metallurgical Research & Development Institute, P.O. Box 87, Helwan
关键词
Hydroxyapatite; Microstructure; Surface treatment; α/β titanium alloys;
D O I
10.1016/j.msec.2019.109974
中图分类号
学科分类号
摘要
The current work aims at exploring the effects of the microstructure and alloy composition on enhancing the bone osseointegration in Ti-6Al-4V (Ti64) and Ti-6Al-7Nb (Ti67) alloys. This was revealed by investigating the alloy susceptibility to grow hydroxyapatite (HA) on their surfaces after immersion in simulated body fluid (SBF). The specimens were produced by two methods: forging and casting in order to study the influence of the microstructure on the precipitation process. The surface conditions investigated were the polished, alkaline and the hydrothermally treated. It was found that precipitation on both of Ti64 and Ti67 occurs after about 4 weeks and considerably dissolve back with further immersion. Precipitation process is enhanced at some pH levels lower than the neutral level. Forged Ti67 has less reactivity with Hank solution than Ti64 specimens; the reverse is true for cast specimens. In case of the alkaline treated specimens, precipitations on cast specimens were denser than on the forged ones. For the hydrothermally treated specimens, high amounts of Ca and P were observed on cast Ti67 indicating that hydrothermal treatment is considered the best surface modification treatment for alloy Ti67. © 2019 Elsevier B.V.
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共 29 条
[1]  
Kikuchi M., Suetsugu Y., Koyama Y.B., Sotone S.C., Itoh S., Takakuda K., Shinomiya K., Edamura K., Nagaoka K., Tanaka S., Bone regeneration materials based on calcium phosphate ceramics, biomaterials in Asia, Commemoration of the 1st Asian Biomaterials Congress, Tsukuba, Japan, January, pp. 327-342, (2008)
[2]  
Elliott J.C., Structure and Chemistry of the Apatites and Other Calcium Orthophosphates, (1994)
[3]  
HinTeoh S., Agrawal M., de Bruijn J.D., Tabata Y., Engineering Materials for Biomedical Applications, Biomaterials Engineering and Processing Series, (2004)
[4]  
Park J., Lakes R.S., Biomaterials, an Introduction, (2007)
[5]  
Kokubo T., Takadama H., How useful is SBF in predicting in vivo bone bioactivity?, Biomaterials, 27, pp. 2907-2915, (2006)
[6]  
Kim H.M., Miyaji F., Kokubo T., Nakamura T., Bonding strength of bone like apatite layer to Ti metal substrate, J. Biomed. Mater. Res., 38, pp. 121-127, (1997)
[7]  
Nazir M., Ting O.P., Swaminathan D., Yee T.S., Muralithran G., Pushparajan K.S., Biomimetic coating of modified titanium surfaces with hydroxyapatite using simulated body fluid, Adv. Mater. Sci. Eng., 2015, (2015)
[8]  
Bordji K., Jouzeau J.Y., Mainard D., Payan E., Delagoutte J.P., Netter P., Evaluation of the effect of three surface treatments on the biocompatibility of 316L stainless steel using human differentiated cells, Biomaterials, 17, pp. 491-500, (1996)
[9]  
El-Hadad S.H., Ibrahim K.M., Wagner L., Characteristics of anodized layer in investment cast Ni50Ti50 shape memory alloy, Journal of Metallurgy, 346328, (2014)
[10]  
El-Hadad S., Ibrahiem K.M., Microstructural effects on corrosion behavior of cast Ti-6.5Al-3.4Mo-1.7Zr alloy, Int. J. Cast Met. Res., 29, pp. 243-250, (2016)