A new type Co(II)-based photocatalyst for the nitrofurantoin antibiotic degradation

被引：84

作者：

Xiang, Ruifang ^{[1
]}

Zhou, Changxin ^{[1
]}

Liu, Yichen ^{[1
]}

Qin, Tianrui ^{[1
]}

Li, Duqingcuo ^{[1
]}

Dong, Xiuyan ^{[1
]}

Muddassir, Mohd. ^{[2
]}

Zhong, Aiguo ^{[3
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Chem Engn, Lanzhou 730070, Peoples R China

[2] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia

[3] Taizhou Univ, Sch Pharmaceut & Chem Engn, Taizhou 31800, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2024年 / 1312卷

关键词：

Nitrofurantoin; Photocatalytic activity; Coordination polymer; Mechanism; ORGANIC FRAMEWORK; COORDINATION; PULMONARY; RESIDUES; ACID;

D O I：

10.1016/j.molstruc.2024.138501

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Coordination polymers (CPs) are a special class of multidimensional materials that can be employed for the photocatalytic degradation of antibiotics in wastewater. In this paper, a new Co(II)-based coordination polymer with the molecular formula {[Co(H2L)(dpa)(H2O)]& sdot;H2O}n (1), (H4L = 1,1 ':2 ',1 ''-triphenyltetracarboxylic acid, dpa = 1,2-di(pyridin-4-yl)diazene) was synthesized and characterized. Single-crystal x-ray diffraction results showed that 1 formed a 2D layered structure, which was stacked into a three-dimensional (3D) supramolecular structure through hydrogen-bonding interactions. In addition, the results of the photocatalytic experiments showed that 1 possesses good photocatalytic activity at nitrofurantoin (NFT). The photocatalytic mechanism has been discussed in detail.

引用

页数：10

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