Preparation of Catalyst Cyclodextrin-Fe-TAML to Activate H2O2 and Oxidize Organic Micropollutants in Water

被引：0
|
作者：
Liu Q.-Q. [1 ]
Cai B.-Z. [1 ]
Cai X.-Y. [1 ]
机构：
[1] Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian
来源：
Huanjing Kexue/Environmental Science | 2023年 / 44卷 / 07期
关键词：
catalyst; CD-Fe-TAML; H[!sub]2[!/sub]O[!sub]2[!/sub; organic micropollutants; oxidation degradation;
D O I：
10.13227/j.hjkx.202208235
中图分类号：
学科分类号：
摘要：
In order to improve the stability and catalytic activity of Fe-TAML, mono-6-oxy-cyclodextrin bonded Fe-TAML catalyst (CD-Fe-TAML) was prepared by bonding Fe-TAML with cyclodextrin (CD) through chlorosulfonylation reaction, metal chelation reaction, and nucleophilic substitution reaction. The catalytic activity and stability of CD-Fe-TAML and the oxidation degradation efficiencies of 34 organic micropollutants such as antibiotics and pesticides by activation of H2O2in water were studied. Compared with that of Fe-TAML, CD-Fe-TAML at pH 7.0 had a 49-fold and 25-fold increase in the rate of activating H2O2to produce iron (Ⅴ/Ⅳ)-oxo intermediates and the degradation rate of the substrate, respectively, and its self-oxidation rate was reduced by 70%. The stability of CD-Fe-TAML was 0.7-699 times higher than that of Fe-TAML in the pH range of 3.0-10.0. Specifically, the stability of CD-Fe-TAML was 33-699 times higher than that of Fe-TAML in the pH range of 3.0-7.0. The sulfonic acid group in the molecular structure of CD-Fe-TAML had an electrophilic effect, which could increase the positive charge density of Fe in the active center, accelerate the O-O bond cleavage of H2O2and the generation of iron(Ⅴ/Ⅳ)-oxo intermediates, improve the catalytic activity of Fe-TAML, and also improve its hydrolysis stability. Meanwhile, the CD group in the molecular structure had the "electron shuttle" effect and inclusion effect. The former could accelerate the electron transfer between the active center Fe-TAML and H2O2to improve the catalytic activity of Fe-TAML. The latter could inhibit the hydrolysis and self-oxidation of the active center Fe-TAML by inclusion or binding of the hydrolysis sites and oxidation sites, thus improving its stability. The degradation efficiencies of micropollutants by CD-Fe-TAML/H2O2under weakly acidic and neutral conditions (in the pH range of 5.0-7.0) were 0.4-59 times higher than those of Fe-TAML/H2O2. The degradation efficiencies of CD-Fe-TAML/H2O2on nine micropollutants with a molar volume less than 0.20 L·mol-1, such as acetamiprid and sulfadiazine, were 0.3-1.1 times higher than that of Fe-TAML/H2O2at pH 8.0, and there were no significant differences between CD-Fe-TAML/H2O2and Fe-TAML/H2O2for micropollutants with a molar volume greater than 0.20 L·mol-1. The results of iodide oxidation by CD-Fe-TAML/H2O2showed that I- was not oxidized to produce iodo-disinfection byproducts (I-DBPs). The degradation of micropollutants by CD-Fe-TAML/H2O2in the surface water sample was not disturbed by water components. The CD-Fe-TAML/H2O2system has a potential application in the removal of organic micropollutants from water. © 2023 Science Press. All rights reserved.
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页码：3978 / 3989
页数：11
相关论文
共 60 条
  • [21] Ike I A, Karanfil T, Cho J, Et al., Oxidation byproducts from the degradation of dissolved organic matter by advanced oxidation processes-a critical review, Water Research, 164, (2019)
  • [22] Chu W H, Xiao R, Ding S K, Et al., Disinfection by-products in drinking water and their control strategies:a review[J], Environmental Science, 42, 11, pp. 5059-5074, (2021)
  • [23] Dong H Y, Qiang Z M, Richardson S D., Formation of iodinated disinfection byproducts (I-DBPs) in drinking water:emerging concerns and current issues[J], Accounts of Chemical Research, 52, 4, pp. 896-905, (2019)
  • [24] Criquet J, Allard S, Salhi E, Et al., Iodate and iodo-trihalomethane formation during chlorination of iodide-containing waters:role of bromide[J], Environmental Science & Technology, 46, 13, pp. 7350-7357, (2012)
  • [25] Collins T J, Ryabov A D., Targeting of high-valent iron-TAML activators at hydrocarbons and beyond[J], Chemical Reviews, 117, 13, pp. 9140-9162, (2017)
  • [26] Liu Q Q, Fu Z Q, Wang Z Y, Et al., Rapid and selective oxidation of refractory sulfur-containing micropollutants in water using Fe-TAML/H2 O2, Applied Catalysis B:Environmental, 315, (2022)
  • [27] Gupta S S, Stadler M, Noser C A, Et al., Rapid total destruction of chlorophenols by activated hydrogen peroxide[J], Science, 296, 5566, pp. 326-328, (2002)
  • [28] Shappell N W, Vrabel M A, Madsen P J, Et al., Destruction of estrogens using Fe-TAML/peroxide catalysis[J], Environmental Science & Technology, 42, 4, pp. 1296-1300, (2008)
  • [29] Chanda A, Khetan S K, Banerjee D, Et al., Total degradation of fenitrothion and other organophosphorus pesticides by catalytic oxidation employing Fe-TAML peroxide activators[J], Journal of the American Chemical Society, 128, 37, pp. 12058-12059, (2006)
  • [30] Su H R, Yu C Y, Zhou Y F, Et al., Quantitative structure-activity relationship for the oxidation of aromatic organic contaminants in water by TAML/H2 O2[J], Water Research, 140, pp. 354-363, (2018)
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