Effect of carbon material additives on hydrogen evolution at rechargeable alkaline iron battery electrodes

被引：0
作者：
Arunkumar P.S. [1 ]
Maiyalagan T. [2 ]
Kheawhom S. [3 ]
Mao S. [4 ]
Jiang Z. [5 ]
机构：
[1] Department of Physics and Nanotechnology, SRM Institute of Science and Technology, Kattankulathur
[2] Electrochemical Energy Laboratory, Department of Chemistry, SRM Institute of Science and Technology, Kattankulathur
[3] Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok
[4] State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai
[5] Key Laboratory of Optical Field Manipulation of Zhejiang Province, Department of Physics, Zhejiang Sci-Tech University, Hangzhou
来源：
Materials Science for Energy Technologies | 2021年 / 4卷
关键词：
Carbon additives; Charge discharge; Iron Air battery; Iron electrode;
D O I：
10.1016/j.mset.2021.06.007
中图分类号：
学科分类号：
摘要：
In recent years a renewed interest in developing iron electrode for iron based accumulators has risen, govern by the progress in nano-materials research that could bring iron based accumulators nearer to their theoretical energy density and capacity. In this aspect, Iron-Air battery chemistry is best suited for current energy crisis in combination with the cost effectiveness, eco-friendliness, recyclability, non-toxicity of the iron materials. The possibility of Iron-Air battery to function as a rechargeable battery makes this electrochemical systems for engaging development. However, some challenges related to the performance of iron electrode needs to be addressed such as the passivation of the iron electrode on discharge due to the accumulation of iron hydroxide and the low efficiency due to the parasitic hydrogen evolution that occurs during the charging. So the proper engineering and the formulation of iron electrodes are necessary to attain the maximum efficiency for Iron-Air battery. In this exertion, different Fe2O3/Carbon (Fe/C) composites are tested as electrodes for Iron air battery. In addition to this, the prepared materials were comprehensively characterized by X-ray diffraction (XRD). The electrochemical effectiveness of the prepared samples were tested in a three electrode configuration.Fe2O3/MWCNT electrode show the best electrochemical performance exhibits a specific capacity of about 350 mAhg−1 at 10 mA cm−2 compared to the Fe2O3/Graphene of 300 mAhg−1, Fe2O3/Acetylene black of 225 mAhg−1 and Fe2O3/Vulcan carbon of 180 mAhg−1. © 2021
引用
收藏
页码：236 / 241
页数：5
相关论文
共 37 条
[1]  
Linden D., Reddy T.B., Iron electrode batteries, handbook of batteries, pp. 251-253, (2002)
[2]  
Falk S.V., Salking A.J., Alkaline storage batteries, (1969)
[3]  
Ojefors L., Carlsson L., An iron-air vehicle battery, J. Power Sour., 2, 3, pp. 287-296, (1978)
[4]  
Falk S.U., Salkind A.J., (1969)
[5]  
Narayanan S.R., Surya Prakash G.K., Manohar A., Yang B., Malkhandi S., Kindler A., Materials challenges and technical approaches for realizing inexpensive and robust iron air batteries for large-scale energy storage, Solid State Ion., 216, pp. 105-109, (2012)
[6]  
Vijayamohanan K., Shukla A.K., Sathyanarayana S., Kinetics of electrode reactions occurring on porous iron electrodes in alkaline media, J. Electroanal. Chem., 289, (1990)
[7]  
McKerracher R.D., PoncedeLeon C., Wills R.G.A., Shah A.A., Walsh F.C., A review of the iron-air secondary battery for energy storage, ChemPlusChem, 80, 2, pp. 323-335, (2015)
[8]  
Kalaignan G.P., Muralidharan V.S., Vasu K.I., Triangular potential sweep voltammetric study of porous iron electrodes in alkali solutions, J. Appl. Electrochem., 17, 5, pp. 1083-1092, (1987)
[9]  
Rajan A.S., Sampath S., Shukla A.K., An in situ carbon-grafted alkaline iron electrode for iron-based accumulators, Energy Environ. Sci., 7, pp. 1110-1116, (2014)
[10]  
Vijayamohanan K., Shukla A.K., Sathyanarayana S., Formation mechanism of porous alkaline iron electrodes, J. Power Sources, 32, 4, pp. 329-339, (1990)
1234