Organic photovoltaic cells with copper(Ⅱ) tetra-methyl substituted phthalocyanine

被引：2
|
作者：
许宗祥 [1 ]
Roy V. A. L [2 ]
机构：
[1] Department of Chemistry, South University of Science and Technology of China
[2] Center of Super Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong
来源：
Chinese Physics B | 2013年 / 22卷 / 12期
关键词：
organic photovoltaic cell; copper(II) tetra-methyl substituted phthalocyanine; π–π; stacking; GIXRD;
D O I：
暂无
中图分类号：
O627.12 [铜族金属有机化合物];
学科分类号：
070303 ; 081704 ;
摘要：
Efficient heterojunction organic photovoltaic（OPV） cells are fabricated based on copper tetra-methyl phthalocyanine（CuMePc） as donor and fullerene（C60） as acceptor. The power conversion efficiency of CuMePc/C60 OPV cell（2.52%） is increased by 88% compared with that of the non-peripheral substituted copper phthalocyanine（CuPc）/C60 OPV cell（1.34%）. The introduction of methyl substituent leads to stronger π–π interaction of CuMePc（;3.5 A） than that of CuPc（;3.8 A）. The efficiency improvement is attributed to the enhanced carrier mobility of CuMePc thin film（1.1×10 3cm2/V·s） and better film morphology by introducing methyl groups into the periphery of CuPc molecule.
引用
收藏
页码：537 / 540
页数：4
相关论文
共 50 条
  • [1] Organic photovoltaic cells with copper (II) tetra-methyl substituted phthalocyanine
    Xu Zong-Xiang
    Roy, V. A. L.
    CHINESE PHYSICS B, 2013, 22 (12)
  • [2] Bulk heterojunction photovoltaic cells based on tetra-methyl substituted copper(II) phthalocyanine:P3HT:PCBM composite
    Xu, Zong-Xiang
    Roy, V. A. L.
    Low, Kam-Hung
    Che, Chi-Ming
    CHEMICAL COMMUNICATIONS, 2011, 47 (34) : 9654 - 9656
  • [3] Tetra-methyl substituted copper (II) phthalocyanine as a hole injection enhancer in organic light-emitting diodes
    Wang, Yu-Long
    Xu, Jia-Ju
    Lin, Yi-Wei
    Chen, Qian
    Shan, Hai-Quan
    Yan, Yan
    Roy, V. A. L.
    Xu, Zong-Xiang
    AIP Advances, 2015, 5 (10):
  • [4] Radiographic investigation on the structure of tetra-methyl ammonium perchlorate and tetra-methyl ammonium permanganate.
    Herrmann, K
    Ilge, W
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1929, 71 (1/2): : 47 - 63
  • [5] On the structure of tetra-methyl hematoporphyrine C.
    O' Daniel, H
    Damaschke, A
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1942, 104 (02): : 114 - 123
  • [6] Planar heterojunction organic photovoltaic cells based on tetramethyl substituted copper(II) phthalocyanine treated with thermal annealing
    Qu, Dalong
    Guo, Runda
    Yue, Shouzhen
    Wu, Yukun
    Yan, Pingrui
    Cheng, Gang
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2014, 47 (41)
  • [7] Near-infrared organic electrophosphorescenct diodes based on Tetra-substituted copper phthalocyanine
    Fan, Zhao-Qi
    Cheng, Chuan-Hui
    Sheng, Ren-Sheng
    Li, Wan-Cheng
    Wang, Jin
    Bai, Qing-Long
    Xia, Dao-Cheng
    Du, Guo-Tong
    Guangdianzi Jiguang/Journal of Optoelectronics Laser, 2010, 21 (04): : 524 - 528
  • [8] SYNTHESIS OF DIMETHYL, TETRA-METHYL AND PENTA-METHYL-HEPTALENES
    HAFNER, K
    HOCK, N
    KNAUP, GL
    MEINHARDT, KP
    TETRAHEDRON LETTERS, 1986, 27 (15) : 1669 - 1672
  • [9] Interdigitated Bulk Heterojunction Organic Photovoltaic Cells With Aligned Copper Phthalocyanine Nanorods
    Zheng, Ying
    Bekele, Robel
    Ouyang, Jiaomin
    Xue, Jiangeng
    IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS, 2010, 16 (06) : 1544 - 1551
  • [10] SYNTHESIS AND BROMINATION OF DIMETHYL, TRI-METHYL AND TETRA-METHYL SUBSTITUTED POLY(ARYL ETHER ETHER KETONE)S
    BEASY, M
    WANG, F
    ROOVERS, J
    POLYMER BULLETIN, 1994, 32 (03) : 281 - 287
12345