Tandem hydroformylation/hydrogenation of olefins to alcohols using atomically dispersed bifunctional catalysts

被引：0

作者：

Ying Zhang ^{[1
]}

Liyang Liu ^{[1
]}

Ziyue Wang ^{[1
]}

Xingcong Zhang ^{[1
]}

Xiaohui He ^{[1
,2
]}

Hongbing Ji ^{[1
,3
]}

机构：

[1] Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, Fine Chemical Industry Research Institute,School of Chemistry, IGCME, Sun Yat-sen University

[2] Guangdong Technology Research Center for Synthesis and Separation of Thermosensitive Chemicals

[3] State Key Laboratory Breeding Base of Green-Chemical Synthesis Technology, Institute of Green Petroleum Processing and Light Hydrocarbon Conversion, College of Chemical Engineering, Zhejiang University of Technology

来源：

Science China(Chemistry) | 2024年 / 67卷 / 11期

关键词：

D O I：

暂无

中图分类号：

TQ223.1 [脂肪族醇]; TQ426 [催化剂（触媒）];

学科分类号：

0817 ; 080502 ; 081705 ;

摘要：

Tandem hydroformylation/hydrogenation of olefins to alcohols is an appealing and challenging route that has received continuous interest. Herein, we report a bifunctional atomically dispersed Rh and Co catalyst（Rh Co/Al2O3-10） prepared by a simple ball milling method that displays superior synergistic catalytic performance（>95% olefins conversion and >80% alcohols selectivity） and broad substrate scope for tandem hydroformylation/hydrogenation reaction, outperforming Rh/Al2O3, Co/Al2O3,and their physically mixed counterparts. In situ CO-DRIFTS, XPS, and kinetic experiments demonstrate that the electron interaction between Rh and Co atoms effectively lowers the apparent activation energy, thus promoting the tandem hydroformylation/hydrogenation reaction. This work not only presents a novel tandem hydroformylation/hydrogenation reaction system for converting olefins to alcohol but also throws light on the rational design of versatile bifunctional catalysts for ondemand synergistic catalysis.

引用

收藏

页码：3706 / 3711

页数：6

相关论文

共 50 条

[21] One-pot Synthesis of Acetals by Tandem Hydroformylation-acetalization of Olefins Using Heterogeneous Supported Catalysts [J].

Li, Xiao ;

Qin, Tingting ;

Li, Liusha ;

Wu, Bo ;

Lin, Tiejun ;

Zhong, Liangshu .

CATALYSIS LETTERS, 2021, 151 (09) :2638-2646

[22] One-pot Synthesis of Acetals by Tandem Hydroformylation-acetalization of Olefins Using Heterogeneous Supported Catalysts [J].

Xiao Li ;

Tingting Qin ;

Liusha Li ;

Bo Wu ;

Tiejun Lin ;

Liangshu Zhong .

Catalysis Letters, 2021, 151 :2638-2646

[23] ASYMMETRIC HYDROFORMYLATION OF OLEFINS USING CHIRAL PLATINUM COMPLEX CATALYSTS [J].

KAWABATA, Y ;

SUZUKI, TM ;

OGATA, I .

CHEMISTRY LETTERS, 1978, (04) :361-362

[24] Tuning the selectivity of catalytic nitriles hydrogenation by structure regulation in atomically dispersed Pd catalysts [J].

Zhibo Liu ;

Fei Huang ;

Mi Peng ;

Yunlei Chen ;

Xiangbin Cai ;

Linlin Wang ;

Zenan Hu ;

Xiaodong Wen ;

Ning Wang ;

Dequan Xiao ;

Hong Jiang ;

Hongbin Sun ;

Hongyang Liu ;

Ding Ma .

Nature Communications, 12

[25] Vicinal Na+ as structure guardians of atomically dispersed Ru catalysts in hydrogenation reactions [J].

Chunyang Dong ;

Ding Ma .

Science China Chemistry, 2020, 63 :1584-1585

[26] Tuning the selectivity of catalytic nitriles hydrogenation by structure regulation in atomically dispersed Pd catalysts [J].

Liu, Zhibo ;

Huang, Fei ;

Peng, Mi ;

Chen, Yunlei ;

Cai, Xiangbin ;

Wang, Linlin ;

Hu, Zenan ;

Wen, Xiaodong ;

Wang, Ning ;

Xiao, Dequan ;

Jiang, Hong ;

Sun, Hongbin ;

Liu, Hongyang ;

Ma, Ding .

NATURE COMMUNICATIONS, 2021, 12 (01)

[27] Vicinal Na+ as structure guardians of atomically dispersed Ru catalysts in hydrogenation reactions [J].

Dong, Chunyang ;

Ma, Ding .

SCIENCE CHINA-CHEMISTRY, 2020, 63 (11) :1584-1585

[28] Tandem Hydroformylation/Hydrogenation of Alkenes to Normal Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst [J].

Takahashi, Kohei ;

Yamashita, Makoto ;

Nozaki, Kyoko .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (45) :18746-18757

[29] Enhanced electrochemical CO2 reduction coupled with urea oxidation using bifunctional atomically dispersed CuNi catalysts [J].

Wu, Wenjie ;

Zhou, Haoyang ;

Liu, Ying ;

Pan, Yifei ;

Chen, Qingqing ;

Zhang, Yu ;

Mao, Junjie ;

Ma, Wenjie ;

Yu, Ping .

NANO RESEARCH, 2025, 18 (01)

[30] ASYMMETRIC OLEFINS HYDROFORMYLATION .6. ASYMMETRIC HYDROFORMYLATION OF ISOMERIC BUTENES USING PLATINUM CATALYSTS [J].

CONSIGLIO, G ;

PINO, P .

HELVETICA CHIMICA ACTA, 1976, 59 (02) :642-645

← 1 2 3 4 5 →