Hierarchical ZnO nanostructured membrane for multifunctional environmental applications

被引:26
作者
Bai, Hongwei [1 ]
liu, Zhaoyang [1 ]
Sun, Darren Delai [1 ]
机构
[1] Nanyang Technol Univ, Sch Civil & Environm Engn, Singapore 639798, Singapore
关键词
Environmental applications; Hierarchical; Membrane; Nut-like" nanostructured material; ZnO; PHOTOCATALYTIC ACTIVITY; WATER-TREATMENT; TIO2; TECHNOLOGY; FABRICATION; FLOWER; GROWTH;
D O I
10.1016/j.colsurfa.2012.05.044
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
To counter the global water crisis such as water resources scarcity and water quality deterioration, membrane filtration has been widely used as a promising technology. Recently, nano-materials and its structured membranes demonstrated multifunctional water purification capability in terms of decontamination and disinfection. Here, hierarchical nitrogen (N)-doped "nut-like" ZnO nanostructured material was hydrothermally synthesized at large scale. This hierarchical N-doped "nut-like" ZnO nanostructured material was well characterized and successfully assembled on a piece of polymer membrane surface to create a multifunctional membrane. This newly developed membrane demonstrated high pollutants removal ability via rejection and photodegradation, and strong antibacterial growth ability under visible light irradiation. At the same time, this novel membrane holds the potential to produce clean water at a constant high flux. The experimental results indicated that the hierarchical N-doped ZnO "nut-like" nanostructured material enhanced the photocatalytic activity in a comparison to commercial ZnO powder. This is caused by enlarging the specific surface area and enhancing the light utilization rate. It is reasonable to believe this hierarchical N-doped "nut-like" ZnO nanostructured membrane would benefit the water purification field. (C) 2012 Elsevier By. All rights reserved.
引用
收藏
页码:11 / 17
页数:7
相关论文
共 35 条
[2]  
Bai H., 2012, CHEM ASIAN J
[3]  
Bai H., 2009, WATER SCI TECH-W SUP, P31
[4]   A hierarchically structured and multifunctional membrane for water treatment [J].
Bai, Hongwei ;
Liu, Zhaoyang ;
Sun, Darren Delai .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 111 :571-577
[5]   Hierarchical ZnO/Cu "corn-like" materials with high photodegradation and antibacterial capability under visible light [J].
Bai, Hongwei ;
Liu, Zhaoyang ;
Sun, Darren Delai .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (13) :6205-6210
[6]   Hierarchically multifunctional TiO2 nano-thorn membrane for water purification [J].
Bai, Hongwei ;
Liu, Zhaoyang ;
Sun, Darren Delai .
CHEMICAL COMMUNICATIONS, 2010, 46 (35) :6542-6544
[7]   Hierarchically organized nanostructured TiO2 for photocatalysis applications [J].
Di Fonzo, F. ;
Casari, C. S. ;
Russo, V. ;
Brunella, M. F. ;
Li Bassi, A. ;
Bottani, C. E. .
NANOTECHNOLOGY, 2009, 20 (01)
[8]   Toxicity of nanosized and bulk ZnO, CuO and TiO2 to bacteria Vibrio fischeri and crustaceans Daphnia magna and Thamnocephalus platyurus [J].
Heinlaan, Margit ;
Ivask, Angela ;
Blinova, Irina ;
Dubourguier, Henri-Charles ;
Kahru, Anne .
CHEMOSPHERE, 2008, 71 (07) :1308-1316
[9]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[10]   Pretreatment for Low Pressure Membranes in Water Treatment: A Review [J].
Huang, Haioo ;
Schwab, Kellogg ;
Jacangelo, Joseph G. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (09) :3011-3019