A Physics-Guided Machine Learning Approach for Capacity Fading Mechanism Detection and Fading Rate Prediction Using Early Cycle Data

Lithium-ion battery development necessitates predicting capacity fading using early cycle data to minimize testing time and costs. This study introduces a hybrid physics-guided data-driven approach to address this challenge by accurately determining the dominant fading mechanism and predicting the average capacity fading rate. Physics-guided features, derived from the electrochemical properties and behaviors within the battery, are extracted from the first five cycles to provide meaningful, interpretable, and predictive data. Unlike previous models that rely on a single regression approach, our method utilizes two separate regression models tailored to the identified dominant fading mechanisms. Our model achieves 95.6% accuracy in determining the dominant fading mechanism using data from the second cycle and a mean absolute percentage error of 17.09% in predicting lifetime capacity fade from the first five cycles. This represents a substantial improvement over state-of-the-art models, which have an error rate approximately three times higher. This study underscores the significance of physics-guided data characterization and the necessity of identifying the primary fading mechanism prior to predicting the capacity fading rate in lithium-ion batteries.