A chemical perspective on the chiral induced spin selectivity effect

被引：9
作者：
Bloom, Brian P. [1 ]
Chen, Zhongwei [2 ]
Lu, Haipeng [2 ]
Waldeck, David H. [1 ]
机构：
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
[2] Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong 999077, Peoples R China
来源：
NATIONAL SCIENCE REVIEW | 2024年 / 11卷 / 09期
基金：
中国国家自然科学基金;
关键词：
chiral; spin selectivity; hybrid organic-inorganic layered material; enantioseparation; MOLECULAR CHIRALITY; WATER OXIDATION; POLARIZATION; ELECTRONS;
D O I：
10.1093/nsr/nwae212
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
This review discusses opportunities in chemistry that are enabled by the chiral induced spin selectivity (CISS) effect. First, the review begins with a brief overview of the seminal studies on CISS. Next, we discuss different chiral material systems whose properties can be tailored through chemical means, with a special emphasis on hybrid organic-inorganic layered materials that exhibit some of the largest spin filtering properties to date. Then, we discuss the promise of CISS for chemical reactions and enantioseparation before concluding. Chiral induced spin selectivity (CISS) provides a new strategy for spin control in enantioselective chemical reactions and separations.
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页数：14
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