A chemical perspective on the chiral induced spin selectivity effect

被引：9
作者：
Bloom, Brian P. [1 ]
Chen, Zhongwei [2 ]
Lu, Haipeng [2 ]
Waldeck, David H. [1 ]
机构：
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
[2] Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong 999077, Peoples R China
来源：
NATIONAL SCIENCE REVIEW | 2024年 / 11卷 / 09期
基金：
中国国家自然科学基金;
关键词：
chiral; spin selectivity; hybrid organic-inorganic layered material; enantioseparation; MOLECULAR CHIRALITY; WATER OXIDATION; POLARIZATION; ELECTRONS;
D O I：
10.1093/nsr/nwae212
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
This review discusses opportunities in chemistry that are enabled by the chiral induced spin selectivity (CISS) effect. First, the review begins with a brief overview of the seminal studies on CISS. Next, we discuss different chiral material systems whose properties can be tailored through chemical means, with a special emphasis on hybrid organic-inorganic layered materials that exhibit some of the largest spin filtering properties to date. Then, we discuss the promise of CISS for chemical reactions and enantioseparation before concluding. Chiral induced spin selectivity (CISS) provides a new strategy for spin control in enantioselective chemical reactions and separations.
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页数：14
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  • [51] Highly Efficient and Tunable Filtering of Electrons' Spin by Supramolecular Chirality of Nanofiber-Based Materials
    Kulkarni, Chidambar
    Mondal, Amit Kumar
    Das, Tapan Kumar
    Grinbom, Gal
    Tassinari, Francesco
    Mabesoone, Mathijs F. J.
    Meijer, E. W.
    Naaman, Ron
    [J]. ADVANCED MATERIALS, 2020, 32 (07)
  • [52] Chirality-induced spin polarization places symmetry constraints on biomolecular interactions
    Kumar, Anup
    Capua, Eyal
    Kesharwani, Manoj K.
    Martin, Jan M. L.
    Sitbon, Einat
    Waldeck, David H.
    Naaman, Ron
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2017, 114 (10) : 2474 - 2478
  • [53] Tailoring the Time-Averaged Structure for Polarization-Sensitive Chiral Perovskites
    Lee, Chan Uk
    Ma, Sunihl
    Ahn, Jihoon
    Kyhm, Jihoon
    Tan, Jeiwan
    Lee, Hyungsoo
    Jang, Gyumin
    Park, Young Sun
    Yun, Juwon
    Lee, Junwoo
    Son, Jaehyun
    Park, Ji-Sang
    Moon, Jooho
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (35) : 16020 - 16033
  • [54] Chirality-Induced Spin Selectivity of Chiral 2D Perovskite Enabling Efficient Spin-Dependent Oxygen Evolution Reaction
    Lee, Hyungsoo
    Ma, Sunihl
    Oh, Seungtae
    Tan, Jeiwan
    Lee, Chan Uk
    Son, Jaehyun
    Park, Young Sun
    Yun, Juwon
    Jang, Gyumin
    Moon, Jooho
    [J]. SMALL, 2023, 19 (40)
  • [55] Metal-Organic Frameworks for Separations
    Li, Jian-Rong
    Sculley, Julian
    Zhou, Hong-Cai
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 869 - 932
  • [56] Spin-Control in Electrocatalysis for Clean Energy
    Liang, Yunchang
    Lihter, Martina
    Lingenfelder, Magali
    [J]. ISRAEL JOURNAL OF CHEMISTRY, 2022, 62 (11-12)
  • [57] Enhancement of electrocatalytic oxygen evolution by chiral molecular functionalization of hybrid 2D electrodes
    Liang, Yunchang
    Banjac, Karla
    Martin, Kevin
    Zigon, Nicolas
    Lee, Seunghwa
    Vanthuyne, Nicolas
    Garces-Pineda, Felipe Andres
    Galan-Mascaros, Jose R.
    Hu, Xile
    Avarvari, Narcis
    Lingenfelder, Magali
    [J]. NATURE COMMUNICATIONS, 2022, 13 (01)
  • [58] Tuning the Circular Dichroism and Circular Polarized Luminescence Intensities of Chiral 2D Hybrid Organic-Inorganic Perovskites through Halogenation of the Organic Ions
    Lin, Jin-Tai
    Chen, Deng-Gao
    Yang, Lan-Sheng
    Lin, Tai-Chun
    Liu, Yi-Hung
    Chao, Yu-Chiang
    Chou, Pi-Tai
    Chiu, Ching-Wen
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (39) : 21434 - 21440
  • [59] Chiral-perovskite optoelectronics
    Long, Guankui
    Sabatini, Randy
    Saidaminov, Makhsud I.
    Lakhwani, Girish
    Rasmita, Abdullah
    Liu, Xiaogang
    Sargent, Edward H.
    Gao, Weibo
    [J]. NATURE REVIEWS MATERIALS, 2020, 5 (06) : 423 - 439
  • [60] Control of light, spin and charge with chiral metal halide semiconductors
    Lu, Haipeng
    Vardeny, Zeev Valy
    Beard, Matthew C.
    [J]. NATURE REVIEWS CHEMISTRY, 2022, 6 (07) : 470 - 485
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