A chemical perspective on the chiral induced spin selectivity effect

被引：9
作者：
Bloom, Brian P. [1 ]
Chen, Zhongwei [2 ]
Lu, Haipeng [2 ]
Waldeck, David H. [1 ]
机构：
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
[2] Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong 999077, Peoples R China
来源：
NATIONAL SCIENCE REVIEW | 2024年 / 11卷 / 09期
基金：
中国国家自然科学基金;
关键词：
chiral; spin selectivity; hybrid organic-inorganic layered material; enantioseparation; MOLECULAR CHIRALITY; WATER OXIDATION; POLARIZATION; ELECTRONS;
D O I：
10.1093/nsr/nwae212
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
This review discusses opportunities in chemistry that are enabled by the chiral induced spin selectivity (CISS) effect. First, the review begins with a brief overview of the seminal studies on CISS. Next, we discuss different chiral material systems whose properties can be tailored through chemical means, with a special emphasis on hybrid organic-inorganic layered materials that exhibit some of the largest spin filtering properties to date. Then, we discuss the promise of CISS for chemical reactions and enantioseparation before concluding. Chiral induced spin selectivity (CISS) provides a new strategy for spin control in enantioselective chemical reactions and separations.
引用
收藏
页数：14
相关论文
共 119 条
  • [1] Spin Selectivity in Photoinduced Charge-Transfer Mediated by Chiral Molecules
    Abendroth, John M.
    Stemer, Dominik M.
    Bloom, Brian P.
    Roy, Partha
    Naaman, Ron
    Waldeck, David H.
    Weiss, Paul S.
    Mondal, Prakash Chandra
    [J]. ACS NANO, 2019, 13 (05) : 4928 - 4946
  • [2] Chiral Aggregates of Triphenylamine-Based Dyes for Depleting the Production of Hydrogen Peroxide in the Photochemical Water-Splitting Process
    Adelizzi, Beatrice
    Rosch, Andreas T.
    van Rijen, Daan J.
    Martire, R. Simone
    Esiner, Serkan
    Lutz, Martin
    Palmans, Anja R. A.
    Meijer, E. W.
    [J]. HELVETICA CHIMICA ACTA, 2019, 102 (05)
  • [3] A new class of chiral semiconductors: chiral-organic-molecule-incorporating organic-inorganic hybrid perovskites
    Ahn, Jihoon
    Lee, Eunsong
    Tan, Jeiwan
    Yang, Wooseok
    Kim, Bokyung
    Moon, Jooho
    [J]. MATERIALS HORIZONS, 2017, 4 (05) : 851 - 856
  • [4] Spin selection in atomic-level chiral metal oxide for photocatalysis
    Ai, Minhua
    Pan, Lun
    Shi, Chengxiang
    Huang, Zhen-Feng
    Zhang, Xiangwen
    Mi, Wenbo
    Zou, Ji-Jun
    [J]. NATURE COMMUNICATIONS, 2023, 14 (01)
  • [5] Enantioselectivity of discretized helical supramolecule consisting of achiral cobalt phthalocyanines via chiral-induced spin selectivity effect
    Aizawa, Hiroki
    Sato, Takuro
    Maki-Yonekura, Saori
    Yonekura, Koji
    Takaba, Kiyofumi
    Hamaguchi, Tasuku
    Minato, Taketoshi
    Yamamoto, Hiroshi M.
    [J]. NATURE COMMUNICATIONS, 2023, 14 (01)
  • [6] Single Nanoparticle Magnetic Spin Memristor
    Al-Bustami, Hammam
    Koplovitz, Guy
    Primc, Darinka
    Yochelis, Shira
    Capua, Eyal
    Porath, Danny
    Naaman, Ron
    Paltiel, Yossi
    [J]. SMALL, 2018, 14 (30)
  • [7] Enhanced Photocatalytic Hydrolysis Performance of Chiral Molecule Loaded Titanium Disulfide Nanosheets
    Bai, Xuesong
    Cao, Yang
    Xu, Yueshan
    Huang, Wei
    Deng, Peilin
    Tian, Xinlong
    Liu, Zhongxin
    Wang, Jieqiong
    Tu, Jinchun
    [J]. CHEMPHYSCHEM, 2022, 23 (12)
  • [8] Separation of enantiomers by their enantiospecific interaction with achiral magnetic substrates
    Banerjee-Ghosh, Koyel
    Ben Dor, Oren
    Tassinari, Francesco
    Capua, Eyal
    Yochelis, Shira
    Capua, Amir
    Yang, See-Hun
    Parkin, Stuart S. P.
    Sarkar, Soumyajit
    Kronik, Leeor
    Baczewski, Lech Tomasz
    Naaman, Ron
    Paltiel, Yossi
    [J]. SCIENCE, 2018, 360 (6395) : 1331 - 1334
  • [9] Magnetization switching in ferromagnets by adsorbed chiral molecules without current or external magnetic field
    Ben Dor, Oren
    Yochelis, Shira
    Radko, Anna
    Vankayala, Kiran
    Capua, Eyal
    Capua, Amir
    Yang, See-Hun
    Baczewski, Lech Tomasz
    Parkin, Stuart Stephen Papworth
    Naaman, Ron
    Paltiel, Yossi
    [J]. NATURE COMMUNICATIONS, 2017, 8
  • [10] Chiral-induced enhanced electrocatalytic behaviour of cysteine coated bifunctional Au-Ni bilayer thin film device for water splitting application
    Bhartiya, Prashant K.
    Srivastava, Manish
    Mishra, Debabrata
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (100) : 42160 - 42170
12345678910