High-performance Na3V2(PO4)3 cathode material embedded in three-dimensional porous carbon derived from tea leaves

被引：0

作者：

Gu, Qingyuan ^{[1
]}

Dai, Maosen ^{[1
]}

Zhang, Xinlei ^{[1
]}

Liu, Zezheng ^{[1
]}

Gong, Kunkun ^{[1
]}

Yang, Yubo ^{[1
]}

Zhao, Taolin ^{[1
,2
,3
]}

机构：

[1] Shijiazhuang Tiedao Univ, Sch Mat Sci & Engn, Shijiazhuang 050043, Peoples R China

[2] Hebei Key Lab Adv Mat Transportat Engn & Environm, Shijiazhuang 050043, Peoples R China

[3] Hebei Engn Res Ctr Metamaterials & Micro Devices, Shijiazhuang 050043, Peoples R China

来源：

CHEMICAL PHYSICS LETTERS | 2024年 / 856卷

基金：

中国国家自然科学基金;

关键词：

Tea leaves; Cathode material; Biomass carbon; Sodium-ion battery; Na3V2(PO4)(3);

D O I：

10.1016/j.cplett.2024.141574

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Among various known positive electrode materials for sodium-ion batteries, polyanion-type cathode materials are the preferred system for high stability and high safety of sodium-ion batteries. Especially, Na3V2(PO4)(3) has enormous development potential. This work uses tea leaves as a novel biomass carbon source to uniformly grow Na3V2(PO4)(3) crystals into a three-dimensional porous carbon framework through a facile sol-gel method. The prepared Na3V2(PO4)(3)/C material presents a three-dimensional porous carbon conductive network structure, and its electrochemical performance is significantly improved compared to the pristine material. The Na3V2(PO4)(3)/C material exhibits a high initial discharge specific capacity of up to 110.6 mAh g(-1) at 0.1 C within 2.0-4.0 V.

引用

页数：8

共 36 条

[1] Polyanion Sodium Vanadium Phosphate for Next Generation of Sodium-Ion Batteries-A Review [J].

Chen, Gongxuan ;

Huang, Qing ;

Wu, Tian ;

Lu, Li .

ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (34)

[2] Insights into the enhanced sodium storage property and kinetics based on the Zr/Si codoped Na3V2(PO4)3/C cathode with superior rate capability and long lifespan [J].

Cheng, Jun ;

Chen, Yanjun ;

Wang, Yanzhong ;

Wang, Chao ;

He, Zhenfeng ;

Li, Dan ;

Guo, Li .

JOURNAL OF POWER SOURCES, 2020, 474

[3] Synthesis of 3-dimensional interconnected porous Na3V2(PO4)3@C composite as a high-performance dual electrode for Na-ion batteries [J].

Didwal, Pravin N. ;

Verma, Rakesh ;

Min, Chan-Woo ;

Park, Chan-Jin .

JOURNAL OF POWER SOURCES, 2019, 413 :1-10

[4] N-Doped Carbon-Layer-Modified Na3V2(PO4)3 as a High-Performance Cathode Material for Sodium-Ion Batteries [J].

Ding, Haiyang ;

He, Xin ;

Tao, Qingdong ;

Zhao, Haomiao ;

Teng, Jinhan ;

Li, Jing .

ENERGY & FUELS, 2022, 36 (17) :10384-10394

[5] Unveiling hybrid Li/Na ions storage mechanism of Na3V2(PO4)3@C cathode for hybrid-ion battery with high-rate performance and ultralong cycle-life [J].

Ge, Yilin ;

Zuo, Zonglin ;

Wang, Feng ;

Xu, Changhong ;

Yao, Qingrong ;

Liu, Peng ;

Wang, Dianhui ;

Luo, Wenbin ;

Deng, Jianqiu .

CHEMICAL ENGINEERING JOURNAL, 2023, 469

[6] Outstanding electrochemical performance of sodium vanadium phosphate cathode co-modified by carbon-coating and titanium-doping for Na-ion batteries [J].

Gu, Yu ;

Xiao, Furen ;

Xu, Kai ;

Pan, Xiaoyan ;

Li, Jin ;

Xu, Caiyun ;

Zhou, Xiaodong .

CERAMICS INTERNATIONAL, 2019, 45 (09) :12570-12574

[7] Homeostatic Solid Solution Reaction in Phosphate Cathode: Breaking High-Voltage Barrier to Achieve High Energy Density and Long Life of Sodium-Ion Batteries [J].

Gu, Zhen-Yi ;

Zhao, Xin-Xin ;

Li, Kai ;

Cao, Jun-Ming ;

Wang, Xiao-Tong ;

Guo, Jin-Zhi ;

Liu, Han-Hao ;

Zheng, Shuo-Hang ;

Liu, Dai-Huo ;

Wu, Hong-Yue ;

Wu, Xing-Long .

ADVANCED MATERIALS, 2024, 36 (23)

[8] Research Progress on Electrochemical Properties of Na3V2(PO4)3 as Cathode Material for Sodium-Ion Batteries [J].

He, Fa ;

Kang, Jiyang ;

Liu, Tongli ;

Deng, Hongjie ;

Zhong, Benhe ;

Sun, Yan ;

Wu, Zhenguo ;

Guo, Xiaodong .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2023, 62 (08) :3444-3464

[9] Partial Modification Strategies of NASICON-Type Na3V2(PO4)3 Materials for Cathodes of Sodium-Ion Batteries: Progress and Perspectives [J].

Huang, Qingke ;

Hu, Zhihua ;

Chen, Kai ;

Zeng, Zeng ;

Sun, Yan ;

Kong, Qingquan ;

Feng, Wei ;

Wang, Ke ;

Li, Zhuangzhi ;

Wu, Zhenguo ;

Chen, Ting ;

Guo, Xiaodong .

ACS APPLIED ENERGY MATERIALS, 2023, 6 (05) :2657-2679

[10] Synthesis and Electrochemical Performance of Uniform Carbon-Coated Na3V2(PO4)(2)F-3 Using Tannic Acid as a Chelating Agent and Carbon Source [J].

Jiang, Ning-Bo ;

Zhang, Lu-Lu ;

Cui, Chen-Xu ;

Gao, Lin ;

Yang, Xue-Lin .

ACS APPLIED ENERGY MATERIALS, 2022, 5 (01) :249-256

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