Synthesis and Optoelectronic Properties of Threaded BODIPYs

被引：1

作者：

Hicguet, Matthieu ^{[1
]}

Mongin, Olivier ^{[1
]}

Leroux, Yann R. ^{[1
]}

Roisnel, Thierry ^{[1
]}

Berree, Fabienne ^{[1
]}

Trolez, Yann ^{[1
]}

机构：

[1] Univ Rennes, ISCR UMR6226, CNRS, Ecole Natl Super Chim Rennes, F-35000 Rennes, France

来源：

CHEMISTRYOPEN | 2024年 / 13卷 / 11期

关键词：

boron; fluorescence; BODIPY; ELECTROGENERATED CHEMILUMINESCENCE; BORON; CHEMISTRY; DYES; COMPLEXES; ACCESS;

D O I：

10.1002/open.202400196

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report on the synthesis of two new threaded BODIPYs 5 and 6 in good yields using boron as a gathering atom and a macrocycle with a 2,2'-biphenol unit. In addition to usual techniques, they were characterized by X-ray crystallography. Their electrochemical and optical properties were investigated. In particular, both compounds are highly emissive with photoluminescence quantum yields of 54 and 81 % respectively. In addition, they both show a high photostability. The synthesis of two new threaded BODIPYs in good yields using boron as a gathering atom is reported. In addition to usual techniques, they were characterized by X-ray crystallography. Their electrochemical and optical properties were investigated. Both compounds are highly emissive with photoluminescence quantum yields up to 81 %. image

引用

页数：5

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