Synthesis and characterization of highly conductive MXene@Bi2O3 electrode material for improved oxygen evolution: the role of electrocatalyst for oxygen evolution reactions

被引:10
作者
Baqais, Amal [1 ]
Shariq, Mohammad [2 ]
Althikrallah, Hanan A. [3 ]
Alshareef, Tasneem H. [4 ]
Alrashdi, Kamelah S. [5 ]
Alharbi, Abdulrahman F. [6 ]
Alhashmialameer, Dalal [7 ]
Ahmed, Imtiaz [8 ]
机构
[1] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 84428, Riyadh 11671, Saudi Arabia
[2] Jazan Univ, Coll Sci, Dept Phys Sci, Phys Div, Jazan 45142, Saudi Arabia
[3] King Faisal Univ, Coll Sci, Dept Chem, Al Hufuf 31982, Al Ahsa, Saudi Arabia
[4] Najran Univ, Coll Sci & Arts, Dept Chem, Najran 11001, Saudi Arabia
[5] Umm Al Qura Univ, Al Qunfudah Univ Coll, Dept Chem, Al Qunfudah 1109, Saudi Arabia
[6] Shaqra Univ, Dept Chem, Coll Sci & Humanities, Al Quwayiyah 19257, Saudi Arabia
[7] Taif Univ, Coll Sci, Dept Chem, Taif 21944, Saudi Arabia
[8] Cent Univ Punjab, Dept Chem, Bathinda 151401, India
来源
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2024年 / 130卷 / 10期
关键词
MXenes; Bi2O3; Nanocomposite; Electrocatalyst; OER; WATER;
D O I
10.1007/s00339-024-07836-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
MXenes are a class of two-layered progress metal carbides/nitrides that offer unique properties for diverse applications, including electrocatalysis, supercapacitors, biosensors, water refinement, and many more. Here, we demonstrate a novel MXene@Bi2O3 heterostructure with boosted electrocatalytic activity for OER. Furthermore, pictures captured by electron microscopy demonstrated MXene's strong cooperation with Bi2O3. Additionally, the 2D MXene cooperation created extra pathways for mass transport during OER. Distinctive structure and the synergistic interaction between its components, MXene@Bi2O3 demonstrates remarkable electrocatalytic activity and durability in alkaline environments. With constant current density of 10 mAcm(-2), the MXene@Bi2O3 catalyst showed outstanding catalytic activity and an overpotential of around 278 mV, which is 85 mV lower than the pure Bi2O3 catalyst. Combining Ti3C2Tx MXene with Bi(2)O(3 )led to increased intrinsic activity and accelerated charge transfer kinetics. This study proposes an effective approach for creating metal oxides and MXene hybrids with distinctive structures for electrocatalytic water splitting. The composite's exceptional electrochemical activity and durability suggest its potential as a very efficient electrocatalyst for water-splitting. Furthermore, this work's design and synthesis of hybrid composites with MXene-based nanomaterials opens up new opportunities for developing novel and efficient electrocatalysts in electrochemical applications.
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页数:9
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