Correlation functions from tensor network influence functionals: The case of the spin-boson model

被引:0
|
作者
Nguyen, Haimi [1 ]
Ng, Nathan [1 ]
Lindoy, Lachlan P. [2 ]
Park, Gunhee [3 ]
Millis, Andrew J. [4 ,5 ]
Kin-Lic Chan, Garnet [6 ]
Reichman, David R. [1 ]
机构
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
[2] Natl Phys Lab, Teddington TW11 0LW, England
[3] CALTECH, Div Engn & Appl Sci, Pasadena, CA 91125 USA
[4] Columbia Univ, Dept Phys, New York, NY 10027 USA
[5] Flatiron Inst, Ctr Computat Quantum Phys, New York, NY 10010 USA
[6] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA
来源
JOURNAL OF CHEMICAL PHYSICS | 2024年 / 161卷 / 10期
基金
英国工程与自然科学研究理事会;
关键词
MECHANICAL RATE CONSTANTS; OPEN QUANTUM-SYSTEMS; DYNAMICS; STATES;
D O I
10.1063/5.0224880
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the application of matrix product state (MPS) representations of the influence functionals (IFs) for the calculation of real-time equilibrium correlation functions in open quantum systems. Focusing specifically on the unbiased spin-boson model, we explore the use of IF-MPSs for complex time propagation, as well as IF-MPSs for constructing correlation functions in the steady state. We examine three different IF approaches: one based on the Kadanoff-Baym contour targeting correlation functions at all times, one based on a complex contour targeting the correlation function at a single time, and a steady state formulation, which avoids imaginary or complex times, while providing access to correlation functions at all times. We show that within the IF language, the steady state formulation provides a powerful approach to evaluate equilibrium correlation functions.
引用
收藏
页数:9
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