Dual-Curing Epoxy Thermosets: Design, Curing, Properties and Applications

被引：8
作者：
Hajebi, Sakineh [1 ]
Payamani, Mahdi [1 ]
Fattahi, Hassan [1 ]
Mortezaei, Mehrzad [1 ]
Jalilolghadr, Sara [1 ]
机构：
[1] Malek Ashtar Univ Technol, Fac Mat & Mfg Technol, Dept Polymer Engn, Tehran, Iran
来源：
POLYMER REVIEWS | 2025年 / 65卷 / 01期
关键词：
Dual-curing; epoxy resin; curing mechanism; click chemistry; thermosetting polymers; INTERPENETRATING POLYMER NETWORKS; THIOL-ENE; CLICK REACTIONS; HYPERBRANCHED POLYMERS; MECHANICAL-PROPERTIES; AMINE SYSTEM; ACRYLATE; RESIN; KINETICS; TEMPERATURE;
D O I：
10.1080/15583724.2024.2405684
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Dual-curing Epoxy thermosets has found widespread use in polymer materials in recent years. Dual-curing system is one of the ways used to control the curing rate of epoxy resin to design the final product through two different curing systems with different reaction conditions. This review begins with an introduction to dual-curing systems based on epoxy and relevant reaction mechanisms. It then provides an overview of the types of dual-curing epoxy resin such as epoxy-acrylate, epoxy-amine, epoxy-thiol, epoxy-siloxane and epoxy-allyl phenol that can be encountered in these systems. Due to the variety of dual-curing models of epoxy resin, different dual-curing models and systems can be used to control the properties of the materials. The review concludes with a review of recent and successful research on dual-cured materials for shape memory polymers, adhesive materials, 3D printed materials, structured surface topologies, and holographic materials. [GRAPHICS] .
引用
收藏
页码：250 / 280
页数：31
相关论文
共 119 条
[1]   Multifunctional allyl-terminated hyperbranched poly(ethyleneimine) as component of new thiol-ene/thiol-epoxy materials [J].
Acebo, Cristina ;
Fernandez-Francos, Xavier ;
Ramis, Xavier ;
Serra, Angels .
REACTIVE & FUNCTIONAL POLYMERS, 2016, 99 :17-25
[2]   PREPREG AGING IN RELATION TO TACK [J].
AHN, KJ ;
PETERSON, L ;
SEFERIS, JC ;
NOWACKI, D ;
ZACHMANN, HG .
JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 45 (03) :399-406
[3]   Time-temperature-transformation (TTT) diagram of a dual-curable off-stoichiometric epoxy-amine system with latent reactivity [J].
Areny, Nuria ;
Konuray, Osman ;
Fernandez-Francos, Xavier ;
Salla, Josep M. ;
Morancho, Josep M. ;
Ramis, Xavier .
THERMOCHIMICA ACTA, 2018, 666 :124-134
[4]   Effect of curing mode on the polymerization characteristics of dual-cured resin cement systems [J].
Arrais, Cesar A. G. ;
Rueggeberg, Frederick A. ;
Waller, Jennifer L. ;
de Goes, Mario F. ;
Giannini, Marcelo .
JOURNAL OF DENTISTRY, 2008, 36 (06) :418-426
[5]   A review on mechanical properties of epoxy nanocomposites [J].
Balguri, Praveen Kumar ;
Samuel, D. G. Harris ;
Thumu, Udayabhaskararao .
MATERIALS TODAY-PROCEEDINGS, 2021, 44 :346-355
[6]   Trialkoxysilane grafting onto nanoparticles for the preparation of clear coat polyacrylate systems with excellent scratch performance [J].
Bauer, F ;
Gläsel, HJ ;
Decker, U ;
Ernst, H ;
Freyer, A ;
Hartmann, E ;
Sauerland, V ;
Mehnert, R .
PROGRESS IN ORGANIC COATINGS, 2003, 47 (02) :147-153
[7]   Epoxy-Based Shape-Memory Actuators Obtained via Dual-Curing of Off-Stoichiometric "Thiol-Epoxy" Mixtures [J].
Belmonte, Alberto ;
Russo, Claudio ;
Ambrogi, Veronica ;
Fernandez-Francos, Xavier ;
De la Flor, Silvia .
POLYMERS, 2017, 9 (03)
[8]   Phenomenological characterization of sequential dual-curing of off-stoichiometric "thiol-epoxy" systems: Towards applicability [J].
Belmonte, Alberto ;
Fernandez-Francos, Xavier ;
Serra, Angels ;
De la Flor, Silvia .
MATERIALS & DESIGN, 2017, 113 :116-127
[9]   3D Printing Thermally Stable High-Performance Polymers Based on a Dual Curing Mechanism [J].
Binyamin, Iris ;
Grossman, Eitan ;
Gorodnitsky, Matanel ;
Kam, Doron ;
Magdassi, Shlomo .
ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (24)
[10]   Microwave curing of epoxy-amine system - effect of curing agent on the rate enhancement [J].
Boey, FYC ;
Yap, BH ;
Chia, L .
POLYMER TESTING, 1999, 18 (02) :93-109
12345678910