Silver bismuth sulphide (AgBiS2)-MXene composite as high-performance electrochemical sensing platform for sensitive detection of pollutant 4-nitrophenol

被引:3
|
作者
Gopi, Praveen Kumar [1 ,2 ]
Sanjayan, C. G. [3 ]
Akhil, S. [3 ]
Ravikumar, Chandan Hunsur [3 ]
Thitamadee, Siripong [1 ,5 ]
Kongpatanakul, Supornchai [1 ]
Balakrishna, R. Geetha [3 ]
Surareungchai, Werasak [1 ,4 ,6 ]
机构
[1] Mahidol Univ, Analyt Sci & Natl Doping Test Inst, Rama 6 Rd, Bangkok 10400, Thailand
[2] King Mongkuts Univ Technol Thonburi, Pilot Plant Dev & Training Inst, Sensor Technol Lab, Bangkhuntien 10150, Bangkok, Thailand
[3] JAIN, Ctr Nano & Mat Sci, Jain Global Campus, Bengaluru 562112, Karnataka, India
[4] King Mongkuts Univ Technol Thonburi, Sch Bioresources & Technol, Bangkhuntien 10150, Bangkok, Thailand
[5] Mahidol Univ, Fac Sci, Dept Physiol, Rama 6Rd, Bangkok 10400, Thailand
[6] King Mongkuts Univ Technol Thonburi, Fac Sci, Nanosci & Nanotechnol Grad Program, Bangkok 10140, Thailand
关键词
MXene; AgBiS2; 4-nitrophenol; Electrocatalysis; Composite; ELECTRODE; NANOSHEETS; SENSOR; GCE;
D O I
10.1016/j.electacta.2024.144616
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
4-Nitrophenol (4-NP) is one of the most common and extensive toxic threats to the environment; hence there is always a need to develop a robust analytical method. In this study, we present MXene-based AgBiS2 nanocomposite as an electrochemical sensing platform for detecting 4-NP. The synergistic combination of MXene and AgBiS2 within the composite structure enhances electrocatalytic performance, resulting in a highly sensitive and selective sensor. The electrochemical performance of the MXene-AgBiS2 modified GCE was evaluated through cyclic voltammetry (CV) and differential pulse voltammetry (DPV) analyses. The sensor exhibited excellent electrochemical properties, including a low detection limit (LOD) of 0.00254 mu M (should consider the method how to get such low LOD - due to 10 times of the lowest conc tested S/N = 3, high sensitivity of 5.862 mu A mu M- 1 cm- 2, and a wide linear range (0.02-1869 mu M). The sensor also demonstrated good selectivity against various interference compounds such as Di-Nitrophenol, Ortho-Nitrophenol, Copper, Cobalt, sodium, Manganese, Zinc, Glucose (GLU), Urea (Ur), Dopamine (DA), Ascorbic acid, and Uric Acid. Along with reproducibility, repeatability, and stability also performed shows, 2.21 %, and 2.71 % respectively. Our nanocomposite sensor, utilizing MXene-based AgBiS2, proves its practicality in real-time tap water analysis. This bridge between lab studies and environmental monitoring marks a significant advancement. The unique properties of our sensor enhance electrochemical sensing, providing a promising solution for swift on-site detection of 4-NP in water, potentially revolutionizing pollutant management.
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页数:11
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