Low-melting mixture solvents: extension of deep eutectic solvents and ionic liquids for broadening green solvents and green chemistry

被引：51

作者：

Chen, Yu ^{[1
]}

Yu, Zhiwu ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, MOE Key Lab Bioorgan Phosphorous Chem & Chem Biol, Beijing 100084, Peoples R China

来源：

GREEN CHEMICAL ENGINEERING | 2024年 / 5卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Green solvents; Deep eutectic solvents; Low transition temperature mixture solvents; Phase diagram; EGaIn; CHOLINE CHLORIDE; CARBOXYLIC-ACIDS; BINARY-MIXTURES; FE-S; PHASE; ELECTROLYTES;

D O I：

10.1016/j.gce.2023.11.001

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Green solvents such as water and ionic liquids (ILs) are pillars of the great mansion of green chemistry and green processing. Initially proposed as a new family of ILs, deep eutectic solvents (DESs) have received fast development in the past two decades. In this contribution, DESs are reviewed critically and the concept is extended to low-melting mixture solvents (LoMMSs), which cover all kinds of materials including ionic compounds, molecular compounds, and metals. Six classes of LoMMSs are proposed as the new classification system and examples are given. Finally, several thermodynamic issues concerning LoMMSs are discussed. Two new concepts, robustness of LoMMSs and high-entropy LoMMSs, are proposed.

引用

页码：409 / 417

页数：9

共 73 条

[1] Binary and ternary deep eutectic solvent mixtures: Influence on methylene blue electropolymerisation [J].

Abad-Gil, Lucia ;

Procopio, Jesus R. ;

Brett, Christopher M. A. .

ELECTROCHEMISTRY COMMUNICATIONS, 2021, 124

[2] Eutectic-based ionic liquids with metal-containing anions and cations [J].

Abbott, Andrew P. ;

Barron, John C. ;

Ryder, Karl S. ;

Wilson, David .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (22) :6495-6501

[3] Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Munro, HL ;

Rasheed, RK ;

Tambyrajah, V .

CHEMICAL COMMUNICATIONS, 2001, (19) :2010-2011

[4] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].

Abbott, AP ;

Boothby, D ;

Capper, G ;

Davies, DL ;

Rasheed, RK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147

[5] Novel solvent properties of choline chloride/urea mixtures [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Rasheed, RK ;

Tambyrajah, V .

CHEMICAL COMMUNICATIONS, 2003, (01) :70-71

[6] Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: the quest for type V DES [J].

Abranches, Dinis O. ;

Martins, Monia A. R. ;

Silva, Liliana P. ;

Schaeffer, Nicolas ;

Pinho, Simao P. ;

Coutinho, Joao A. P. .

CHEMICAL COMMUNICATIONS, 2019, 55 (69) :10253-10256

[7]

Anderson T.J., 1991, J. Phase Equilib, V12, P64, DOI DOI 10.1007/BF02663677

[8] Anomalous pressure dependent phase diagram of liquid Ga-In alloys [J].

Ben Shalom, Shir ;

Kim, Han Gyeol ;

Emuna, Moran ;

Argaman, Uri ;

Greenberg, Yaron ;

Lee, Joonho ;

Yahel, Eyal ;

Makov, Guy .

JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 822

[9] Deep eutectic solvents based on N-methylacetamide and a lithium salt as suitable electrolytes for lithium-ion batteries [J].

Boisset, Aurelien ;

Menne, Sebastian ;

Jacquemin, Johan ;

Balducci, Andrea ;

Anouti, Meriem .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (46) :20054-20063

[10] Novel zwitterionic deep eutectic solvents from trimethylglycine and carboxylic acids: characterization of their properties and their toxicity [J].

Cardellini, Fabio ;

Tiecco, Matteo ;

Germani, Raimondo ;

Cardinali, Gianluigi ;

Corte, Laura ;

Roscini, Luca ;

Spreti, Nicoletta .

RSC ADVANCES, 2014, 4 (99) :55990-56002

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