A multifunctional interlayer between mesoporous TiO2 and perovskite for perovskite solar cells with high efficiency and stability

被引:0
|
作者
Huang, Wen-Jie [1 ]
Zhang, Zhen-Long [1 ]
Liu, Yue-Feng [1 ]
Gao, Hui-Ping [1 ]
Mao, Yan-Li [1 ,2 ]
机构
[1] Henan Univ, Sch Phys & Elect, Kaifeng 475004, Peoples R China
[2] Int Joint Res Lab New Energy Mat & Devices Henan P, Kaifeng 475004, Peoples R China
基金
中国国家自然科学基金;
关键词
perovskite solar cells; multifunctional interlayer; efficiency and stability; DOPED TIO2; PERFORMANCE; INTERFACE; ER3+; YB3+;
D O I
10.1088/1402-4896/ad7653
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The industrialization of the perovskite solar cells (PSCs) requires further lifting their power conversion efficiency (PCE). There are some important factors to hinder the PCE improvement, such as interface defects and energy level mismatching betwee electron transport layer (ETL) and perovskite layer, and solar energy loss due to no absorption of near infrared (NIR) for the perovsktie. Thus in this study, a multifunctional material of W-Er-Yb doped TiO2 (W-UC-TiO2) was prepared and applied to PSCs as an interlayer between mesoporous TiO2 and perovskite. The experimental results demonstrate that the interlayer of W-UC-TiO2 has the functions of improving NIR absorption for PSCs, passivating inerface defects and improving energy level matching between TiO2 and perovskite. A high efficiency of 21.32% was acquired for the PSCs with W-UC-TiO2 interlayer from 19.26% for the control device. Moreover, stability of the PSCs was improved by the insertion of W-UC-TiO2 interlayer.
引用
收藏
页数:9
相关论文
共 50 条
  • [21] Multifunctional Aminoglycoside Antibiotics Modified SnO2 Enabling High Efficiency and Mechanical Stability Perovskite Solar Cells
    Yan, Tong
    Zhang, Chenxi
    Li, Shiqi
    Wu, Yukun
    Sun, Qinjun
    Cui, Yanxia
    Hao, Yuying
    ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (28)
  • [22] Enhanced Efficiency and Stability of Perovskite Solar Cells Through Nd-Doping of Mesostructured TiO2
    Roose, Bart
    Godel, Karl C.
    Pathak, Sandeep
    Sadhanala, Aditya
    Baena, Juan Pablo Correa
    Wilts, Bodo D.
    Snaith, Henry J.
    Wiesner, Ulrich
    Gratzel, Michael
    Steiner, Ullrich
    Abate, Antonio
    ADVANCED ENERGY MATERIALS, 2016, 6 (02)
  • [23] Scalable Processing of Low-Temperature TiO2 Nanoparticles for High-Efficiency Perovskite Solar Cells
    Hossain, Ihteaz M.
    Hudry, Damien
    Mathies, Florian
    Abzieher, Tobias
    Moghadamzadeh, Somayeh
    Rueda-Delgado, Diana
    Schackrnar, Fabian
    Bruns, Michael
    Andriessen, Ronn
    Aernouts, Tom
    Di Giacomo, Francesco
    Lemmer, Uli
    Richards, Bryce S.
    Paetzold, Ulrich W.
    Hadipour, Afshin
    ACS APPLIED ENERGY MATERIALS, 2019, 2 (01) : 47 - 58
  • [24] Sputtering of TiO2 for High-Efficiency Perovskite and 23.1% Perovskite/Silicon 4-Terminal Tandem Solar Cells
    Lee, Sang-Won
    Bae, Soohyun
    Cho, Kyungjin
    Kim, Seongtak
    Hwang, Jae-Keun
    Lee, Wonkyu
    Lee, Solhee
    Hyun, Ji Yeon
    Lee, Seunghun
    Choi, Sung Bin
    Chun, Hongpil
    Kim, Won Mok
    Kang, Yoonmook
    Lee, Hae-Seok
    Kim, Donghwan
    ACS APPLIED ENERGY MATERIALS, 2019, 2 (09): : 6263 - 6268
  • [25] Multifunctional Interface Treatment of Phosphate for High-Efficiency Perovskite Solar Cells
    Zou, Yihui
    Lin, Changhong
    Hu, Haihua
    Li, Huilin
    Lin, Ping
    Wang, Peng
    Xu, Lingbo
    Wu, Xiaoping
    Cui, Can
    ACS APPLIED ENERGY MATERIALS, 2023, 6 (19) : 9994 - 10004
  • [26] Modifying Mesoporous TiO2 by Ammonium Sulfonate Boosts Performance of Perovskite Solar Cells
    Zhang, Mengmeng
    Zhou, Weiran
    Hu, Wanpei
    Li, Bairu
    Qiao, Qiquan
    Yang, Shangfeng
    ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (11) : 12696 - 12705
  • [27] Planar Heterojunction Perovskite Solar Cells with TiO2 Scaffold in Perovskite Film
    Wang, Peng
    Zhang, Jing
    Chen, Renjie
    Zeng, Zhaobing
    Huang, Xiaokun
    Wang, Liming
    Xu, Jie
    Hu, Ziyang
    Zhu, Yuejin
    ELECTROCHIMICA ACTA, 2017, 227 : 180 - 184
  • [28] Improved Efficiency and Stability of Perovskite Solar Cells Using the Multifunctional Additive Au Clusters
    Li, Yu
    Hu, Hangyu
    Jin, Mengqi
    Feng, Yan
    Shen, Zhitao
    Liu, Ying
    Liu, Rong
    Li, Huilin
    Li, Fumin
    Chen, Chong
    ACS APPLIED ENERGY MATERIALS, 2022, 5 (10): : 12663 - 12672
  • [29] Multifunctional molecular modulators for perovskite solar cells with over 20% efficiency and high operational stability
    Bi, Dongqin
    Li, Xiong
    Milic, Jovana, V
    Kubicki, Dominik J.
    Pellet, Norman
    Luo, Jingshan
    Lagrange, Thomas
    Mettraux, Pierre
    Emsley, Lyndon
    Zakeeruddin, Shaik M.
    Gratzel, Michael
    NATURE COMMUNICATIONS, 2018, 9
  • [30] Interface engineering of TiO2/perovskite interface via fullerene derivatives for high performance planar perovskite solar cells
    Guo, Xing
    Zhang, Bingjuan
    Lin, Zhenhua
    Ma, Jing
    Su, Jie
    Zhu, Weidong
    Zhang, Chunfu
    Zhang, Jincheng
    Chang, Jingjing
    Hao, Yue
    ORGANIC ELECTRONICS, 2018, 62 : 459 - 467