Effects of particle size and flow properties on the performance of ceramic-coated separators in Lithium-ion batteries

被引:1
|
作者
Oh, Ji-hui [1 ,2 ]
Han, Joo-Young [1 ]
Hyun, Da-Eun [2 ,3 ]
Jung, Min-Gi [2 ,4 ]
Koo, Sang-Mo [1 ]
Kim, Sunghoon [5 ]
Kim, Yong-Nam [2 ]
Lee, Dong-Won [2 ]
Shin, Weon Ho [1 ]
Oh, Jong-Min [1 ]
机构
[1] Kwangwoon Univ, Dept Elect Mat Engn, Seoul 01897, South Korea
[2] Korea Testing Lab, Mat Technol Ctr, Seoul 08389, South Korea
[3] Korea Univ, Dept Mat Sci & Engn, Seoul 02841, South Korea
[4] Hanyang Univ, Dept Mat Sci & Chem Engn, Ansan 15588, South Korea
[5] Dong Eui Univ, Ctr Brain Busan Plus Program 21, Appl Chem, Busan 47227, South Korea
基金
新加坡国家研究基金会;
关键词
Flow properties; Boehmite powder; Boehmite-coated separator; Thermal stability; Lithium-ion battery; ROTATING DRUM; SEGREGATION;
D O I
10.1016/j.powtec.2024.120139
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This study investigates the relationship between particle size and flow properties of boehmite powders and their impact on ceramic-coated separators for lithium-ion batteries, specifically exploring how these properties influence the performance of the separators. The separators coated with BH-3 powder, with larger sizes and better flow properties than BH-1 and BH-2, showed superior characteristics with the minimum deviation when measuring physical properties such as thickness and roughness. The BH-3 coated separators, with <10% shrinkage at 150 degrees C for 1 h, showed the highest ion conductivity (0.69 mS cm(-1)) and superior electrochemical properties compared to bare PE separators. These results highlight the importance of the excellent flow properties of the boehmite powders, which reduces the slurry viscosity, facilitates the formation of a uniform coating layer, and consequently enhances the performance of the separator.
引用
收藏
页数:8
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