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Lanthanide hydrogels with tunable circularly polarized luminescence (CPL) via supramolecular chirality induction
被引:1
|作者:
Laishram, Raju
[1
,2
,4
]
Sarkar, Souvik
[1
,2
]
Maitra, Uday
[3
]
George, Subi J.
[1
,2
]
机构:
[1] Jawaharlal Nehru Ctr Adv Sci Res JNCASR Jakkur, New Chem Unit, Bangalore 560064, India
[2] Jawaharlal Nehru Ctr Adv Sci Res JNCASR Jakkur, Sch Adv Mat, Bangalore 560064, India
[3] Indian Inst Sci, Dept Organ Chem, Bengaluru, India
[4] Manipur Univ, Dept Chem, Indo Myanmar Road, Imphal 795003, Manipur, India
关键词:
ASSEMBLIES;
DICHROISM;
D O I:
10.1039/d4tc03257h
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
Lanthanide-derived materials are promising candidates for efficient circularly polarized luminescence (CPL) with a high dissymmetry factor (g(lum)). However, synthesizing chiral ligands in lanthanide-based designs remains challenging. In this context, we present a simpler, modular approach using 'supramolecular chirality induction' and non-covalent sensitization to create soft hydrogel materials with tunable CPL emission and a remarkably high g(lum) of 2 x 10(-2).
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页码:15418 / 15422
页数:5
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