Lanthanide hydrogels with tunable circularly polarized luminescence (CPL) via supramolecular chirality induction

被引:1
|
作者
Laishram, Raju [1 ,2 ,4 ]
Sarkar, Souvik [1 ,2 ]
Maitra, Uday [3 ]
George, Subi J. [1 ,2 ]
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res JNCASR Jakkur, New Chem Unit, Bangalore 560064, India
[2] Jawaharlal Nehru Ctr Adv Sci Res JNCASR Jakkur, Sch Adv Mat, Bangalore 560064, India
[3] Indian Inst Sci, Dept Organ Chem, Bengaluru, India
[4] Manipur Univ, Dept Chem, Indo Myanmar Road, Imphal 795003, Manipur, India
关键词
ASSEMBLIES; DICHROISM;
D O I
10.1039/d4tc03257h
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Lanthanide-derived materials are promising candidates for efficient circularly polarized luminescence (CPL) with a high dissymmetry factor (g(lum)). However, synthesizing chiral ligands in lanthanide-based designs remains challenging. In this context, we present a simpler, modular approach using 'supramolecular chirality induction' and non-covalent sensitization to create soft hydrogel materials with tunable CPL emission and a remarkably high g(lum) of 2 x 10(-2).
引用
收藏
页码:15418 / 15422
页数:5
相关论文
共 50 条
  • [1] Control of circularly polarized luminescence (CPL) properties by supramolecular complexation
    Imai, Yoshitane
    Kawano, Kenta
    Nakano, Yoko
    Kawaguchi, Kakuhiro
    Harada, Takunori
    Sato, Tomohiro
    Fujiki, Michiya
    Kuroda, Reiko
    Matsubara, Yoshio
    NEW JOURNAL OF CHEMISTRY, 2008, 32 (07) : 1110 - 1112
  • [2] Tunable Circularly Polarized Luminescence via Chirality Induction and Energy Transfer from Organic Films to Semiconductor Nanocrystals
    Parzyszek, Sylwia
    Tessarolo, Jacopo
    Pedrazo-Tardaos, Adrian
    Ortuno, Ana M.
    Baginski, Maciej
    Bals, Sara
    Clever, Guido H.
    Lewandowski, Wiktor
    ACS NANO, 2022, 16 (11) : 18472 - 18482
  • [3] Eutectogels as Matrices to Manipulate Supramolecular Chirality and Circularly Polarized Luminescence
    Cheng, Qiuhong
    Hao, Aiyou
    Xing, Pengyao
    ACS NANO, 2022, 16 (04) : 6825 - 6834
  • [4] Chirality Induction on a Coordination Capsule for Circularly Polarized Luminescence
    Harada, Kentaro
    Sekiya, Ryo
    Haino, Takeharu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (39)
  • [5] Achiral isomers controlled circularly polarized luminescence in supramolecular hydrogels
    Yang, Li
    Wang, Fang
    Auphedeous, Dang-i Y.
    Feng, Chuanliang
    NANOSCALE, 2019, 11 (30) : 14210 - 14215
  • [6] Inversing supramolecular chirality and boosting circularly polarized luminescence of pyrene moieties via a gel matrix
    Bai, Xue
    Jiang, Yuqian
    Zhao, Guangjiu
    Jiang, Jian
    Yuan, Chenhuan
    Liu, Minghua
    SOFT MATTER, 2021, 17 (16) : 4328 - 4334
  • [7] Tunable Stokes shift and circularly polarized luminescence by supramolecular gel
    Jintoku, Hirokuni
    Kao, Min-Tzu
    Del Guerzo, Andre
    Yoshigashima, Yudai
    Masunaga, Takuya
    Takafuji, Makoto
    Ihara, Hirotaka
    JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (23) : 5970 - 5975
  • [8] Lanthanide-DNA supramolecular hydrogels with tunable and responsive luminescence
    YANG Sen
    PAN XiaoRui
    TANG JianPu
    YAO Chi
    YANG DaYong
    ScienceChina(TechnologicalSciences), 2022, 65 (05) : 1043 - 1051
  • [9] Lanthanide-DNA supramolecular hydrogels with tunable and responsive luminescence
    Yang Sen
    Pan XiaoRui
    Tang JianPu
    Yao Chi
    Yang DaYong
    SCIENCE CHINA-TECHNOLOGICAL SCIENCES, 2022, 65 (05) : 1043 - 1051
  • [10] Lanthanide-DNA supramolecular hydrogels with tunable and responsive luminescence
    YANG Sen
    PAN XiaoRui
    TANG JianPu
    YAO Chi
    YANG DaYong
    Science China Technological Sciences, 2022, (05) : 1043 - 1051