Enhancing strength and ductility of extruded Ti-alloy-reinforced Al-Mg-Si composites: Roles of interface nanostructures and chemical bonding

A comprehensive understanding of interface nanostructures and chemical interactions is required for solving the strength-plasticity trade-off dilemma of Al/Ti composites. Continuously Tireinforced Al-matrix composites with superior strength and ductility are fabricated via a novel extrusion technique. The unique strain-hardening mechanism of the Al/Ti composite plates at low strains is attributed to the coupling effects of the strong interface constraint potency, the mechanical incompatibility between the soft Al and hard alpha-Ti, and a large elastic strain of hard alpha-Ti. Interlocking structures with atomic interdiffusion are observed at the Al/Ti interface. Mechanical and thermal effects induce lattice distortion and atomic superdiffusion, thus resulting in an interfacial intermixing zone with substantial dislocations and misfit strain. These characteristics produce a strong interface constraint effect during tensile, causing superior strain/dislocation hardening and uniform plasticity. Nanoclusters with cubic structures and dispersed dislocations are detected in the three-dimensional (3D) atomic intermixing zone at the Al/TiAl3 interface, accompanied by the aggregation of Mg. The nanostructures with numerous dislocations in the 3D Ti/TiAl3 transition zone feature lattices with partially tetragonal structures and ordered Ti-Al(Si) clusters. Ab initio calculations indicate that the strong chemical interaction between Si and Ti atoms not only improves the interface bonding strength, but also disturbs the lattices and broadens the transition zone. Moreover, the 3D interface transition zones, accompanied by dispersed dislocations, improve the interface constraint potency and hardening capability of the annealed Al/Ti composite plate. This work sheds light on the capability of the extrusion technique to produce fiber-reinforced Al-matrix composites with superior mechanical properties and provides new strategies for improving the chemical bonding strength and interface constraint effect via the interface invasion of specific elements.