Benzothiadiazole-based water-soluble macrocycle: Synthesis, aggregation-induced emission and selective detection of spermine

被引：4

作者：

Li, Shuo ^{[1
,2
]}

Liu, Qianfa ^{[1
,2
]}

Mao, Lijun ^{[1
,2
]}

Zhang, Xin ^{[1
,2
]}

Li, Chunju ^{[3
]}

Ma, Da ^{[1
,2
]}

机构：

[1] Taizhou Univ, Sch Pharmaceut Engn, Taizhou 318000, Peoples R China

[2] Taizhou Univ, Inst Adv Studies, Taizhou 318000, Peoples R China

[3] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2024年 / 35卷 / 11期

基金：

中国国家自然科学基金;

关键词：

Macrocycle; Water-soluble; Aggregation-induced emission; Biogenic amines; Host-guest interaction; HOST-GUEST; FLUORESCENCE DETECTION; TETRAPHENYLETHYLENE;

D O I：

10.1016/j.cclet.2024.109791

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reported here is the synthesis of a new macrocycle bearing anionic carboxylate groups with water-soluble aggregation-induced emission (AIE). The water-soluble macrocycle without typical AIE luminogens is constructed based on the building block of benzothiadiazole. It exhibits a remarkable AIE effect. This watersoluble macrocycle can selectively bind different types of biogenic amines in aqueous media with the tightest binding towards spermine. The fluorescence enhancement induced by supramolecular encapsulation is used to detect spermine. (c) 2024 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.

引用

页数：4

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