The impact of diffusiophoresis on hydrodynamic dispersion and filtration in porous media

It is known that the dispersion of colloidal particles in porous media is determined by medium structure, pore-scale flow variability and diffusion. However, much less is known about how diffusiophoresis, that is, the motion of colloidal particles along salt gradients, impacts large-scale particle dispersion in porous media. To shed light on this question, we perform detailed pore-scale simulations of fluid flow, solute transport and diffusiophoretic particle transport in a two-dimensional hyper-uniform porous medium. Particles and solute are initially uniformly distributed throughout the medium. The medium is flushed at constant flow rate, and particle breakthrough curves are recorded at the outlet to assess the macroscopic effects of diffusiophoresis. Particle breakthrough curves show non-Fickian behaviour manifested by strong tailing that is controlled by the diffusiophoretic mobility. Although diffusiophoresis is a short-time, microscopic phenomenon owing to the fast attenuation of salt gradients, it governs macroscopic colloid dispersion through the partitioning of particles into transmitting and dead-end pores. We quantify these behaviours by an upscaled analytical model that describes both the retention and release of colloids in dead-end pores and the observed long-time tailings. Our results suggest that diffusiophoresis is an efficient tool to control particle dispersion and filtration through porous media.