Enhancing Li+ transfer efficiency and strength of PEO-based composite solid electrolyte for long stable cycling of all-solid-state lithium metal batteries

被引：2

作者：

Song, Xin ^{[1
]}

Ma, Kang ^{[2
]}

Wang, Han ^{[1
]}

Wang, Jian ^{[1
]}

Chen, Jiawei ^{[1
]}

Zheng, Zongmin ^{[1
]}

Zhang, Jianmin ^{[1
]}

机构：

[1] Qingdao Univ, Coll Mech & Elect Engn, Power & Energy Storage Syst Res Ctr, Qingdao 266071, Peoples R China

[2] Qingdao Univ, Sch Mat Sci & Engn, Qingdao 266071, Peoples R China

来源：

COMPOSITES COMMUNICATIONS | 2024年 / 50卷

关键词：

All-solid-state batteries; Metal-organic frameworks; Cellulose; Long cycle life;

D O I：

10.1016/j.coco.2024.102013

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

The metal-organic frameworks (Zeolitic imidazolate framework-67, ZIF-67) were in-situ grown on the cellulose skeleton surfaces which are rich in hydroxyl groups, and combined with PEO-based electrolytes to form composite solid electrolytes (CSEs). The assembled Li/CSEs/Li exhibit an ultra-long cycle life (>2000 h, 50 C-degrees; >2500 h, 30 C-degrees) and excellent lithium-ion transference efficiency (t(Li+) = 0.46) at 50 C-degrees. This work provides a new pathway for the development of high-safety and low-cost all-solid-state batteries.

引用

页数：7

共 25 条

[11] Bacterial Cellulose Composite Solid Polymer Electrolyte With High Tensile Strength and Lithium Dendrite Inhibition for Long Life Battery
Li, Yuhan
Sun, Zongjie
Liu, Dongyu
Lu, Shiyao
Li, Fei
Gao, Guoxin
Zhu, Min
Li, Mingtao
Zhang, Yanfeng
Bu, Huaitian
Jia, Zhiyu
Ding, Shujiang
[J]. ENERGY & ENVIRONMENTAL MATERIALS, 2021, 4 (03) : 434 - 443
[12] Designing polymers for advanced battery chemistries
Lopez, Jeffrey
Mackanic, David G.
Cui, Yi
Bao, Zhenan
[J]. NATURE REVIEWS MATERIALS, 2019, 4 (05) : 312 - 330
[13] Balancing interfacial reactions to achieve long cycle life in high-energy lithium metal batteries
Niu, Chaojiang
Liu, Dianying
Lochala, Joshua A.
Anderson, Cassidy S.
Cao, Xia
Gross, Mark E.
Xu, Wu
Zhang, Ji-Guang
Whittingham, M. Stanley
Xiao, Jie
Liu, Jun
[J]. NATURE ENERGY, 2021, 6 (07) : 723 - 732
[14] Powering the future: application of cellulose-based materials for supercapacitors
Perez-Madrigal, Maria M.
Edo, Miquel G.
Aleman, Carlos
[J]. GREEN CHEMISTRY, 2016, 18 (22) : 5930 - 5956
[15] Enabling Stable Cycling of 4.2 V High-Voltage All-Solid-State Batteries with PEO-Based Solid Electrolyte
Qiu, Jiliang
Liu, Xinyu
Chen, Rusong
Li, Qinghao
Wang, Yi
Chen, Penghao
Gan, Luyu
Lee, Sang-Jun
Nordlund, Dennis
Liu, Yijin
Yu, Xiqian
Bai, Xuedong
Li, Hong
Chen, Liquan
[J]. ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (22)
[16] Spinodal wrinkling in thin-film poly(ethylene oxide)/polystyrene bilayers
Sharp, JS
Vader, D
Forrest, JA
Smith, MI
Khomenko, M
Dalnoki-Veress, K
[J]. EUROPEAN PHYSICAL JOURNAL E, 2006, 19 (04) : 423 - 432
[17] Issues and challenges facing rechargeable lithium batteries
Tarascon, JM
Armand, M
[J]. NATURE, 2001, 414 (6861) : 359 - 367
[18] Cellulose-based Supercapacitors: Material and Performance Considerations
Wang, Zhaohui
Tammela, Petter
Stromme, Maria
Nyholm, Leif
[J]. ADVANCED ENERGY MATERIALS, 2017, 7 (18)
[19] Double-network composite solid electrolyte with stable interface for dendrite-free Li metal anode
Wu, Feng
Wen, Ziyue
Zhao, Zhikun
Bi, Jiaying
Shang, Yanxin
Liang, Yaohui
Li, Li
Chen, Nan
Li, Yuejiao
Chen, Renjie
[J]. ENERGY STORAGE MATERIALS, 2021, 38 : 447 - 453
[20] Homogeneous and Fast Ion Conduction of PEO-Based Solid-State Electrolyte at Low Temperature
Xu, Shengjun
Sun, Zhenhua
Sun, Chengguo
Li, Fan
Chen, Ke
Zhang, Zhihao
Hou, Guangjin
Cheng, Hui-Ming
Li, Feng
[J]. ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (51)

← 1 2 3 →