Degradation of acid blue 41 with carbon quantum dots@MOF-808 nanocomposite as a biocompatible photocatalyst under visible light

被引:4
|
作者
Ghasemzadeh, Roghayyeh [1 ]
Akhbari, Kamran [1 ]
机构
[1] Univ Tehran, Coll Sci, Sch Chem, Tehran 141556455, Iran
基金
美国国家科学基金会;
关键词
Carbon quantum dots; MOF-808; Template; Nanocomposite; Photocatalyst; METAL-ORGANIC FRAMEWORKS; METHANE STORAGE; DOTS; HETEROJUNCTION; CONTAMINANTS; ADSORPTION; NANOSHEETS; REMOVAL;
D O I
10.1016/j.jphotochem.2024.115984
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CQDs@MOF-808 guest@host nanocomposite as a biocompatible photocatalyst has been synthesized using a shipbottle approach involving the impregnation method for immobilization of glucose molecules as carbon quantum dots (CQDs) precursor into the MOF-808 pores to form Glucose@MOF-808 and further fabrication of carbon quantum dots (CQDs) via in-situ thermolysis route of glucose molecules loaded into the pores of MOF-808. The photocatalytic degradation efficiency of 86.62 % was calculated for CQDs@MOF-808 nanocomposite for degradation of Acid Blue 41 in 120 min under visible light irradiation, that was attributed to the presence of CQDs inside MOF-808 pores. The exceptional characteristics of CQDs include outstanding up-converted photoluminescence (UCPL) effects, photo-induced electron transfer, electron reservoir properties, and electron-hole separations, all contributing to the photocatalytic degradation of Acid Blue 41. The synthesized samples were characterized by PXRD, FT-IR, EDX, N2 adsorption-desorption isotherm, TEM, DRS, PL, EIS and Mott - Sckottky measurements.
引用
收藏
页数:12
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