Provincial emission inventory of atmospheric polycyclic aromatic hydrocarbons (PAHs) in China

China, as the largest global emitter of atmospheric polycyclic aromatic hydrocarbons (PAHs), exhibits significant variation in energy structure and technological capabilities among provinces. It is vital to construct a provinciallevel emission inventory of PAHs, fully considering these provincial disparities, for assessing the environmental budgets and instituting effective mitigation measures. This study constructed a dataset of provincial PAHs emission factors based on downscaling estimates by incorporating the Human Development Index (HDI). These emission factors were combined with the latest activity rate data to estimate PAHs emissions from individual provinces in China from 2007 to 2017. The national total PAHs emissions in our study were 11.8-12.3% higher than the previous emission inventory results. The validation results indicated that the inventory-based PAHs emissions were significantly correlated with the simulated emissions by an atmospheric box model and watershed model. From 2007 to 2017, nearly three-quarters of provinces declined in PAHs emissions resulting from technological advancements and environmental standard improvements, leading to a 34.4% reduction (from 118.5 to 77.8 Gg) of the national total. The industrial sector was consistently the dominant contributor (51.9-66.4%) with a growing trend in its share. This growth was dominantly contributed by less developed provinces, such as Heilongjiang, Ningxia, and Qinghai, indicating that there was a shift of industrial sectors and associated PAHs emissions from highly concentrated industrial regions to nascent industrial regions. This study provides essential data support for a comprehensive understanding of each province's emission responsibilities regarding PAHs and for assessing the potential risks that PAHs pose to human health and ecosystems in these provinces.