Z-scheme heterojunction enhanced photocatalytic performance for CO2 reduction to CH4

Due to the high charge separation efficiency leading to high photocatalytic activity, there has been significant interest in enhancing the charge separation ability of photocatalysts by controlling the heterojunction structure. To investigate the effect of the heterojunction structure on the photocatalytic performance of composite catalysts and understand its corresponding mechanism, a Z-scheme ZnFe2O4/ZnO/CdS heterojunction was constructed using the ultrasound method and used for CO2 photoreduction. The Z-scheme heterojunction catalyst demonstrates elevated photocatalytic and charge separation efficiencies. Specifically, the conversion rate for the photocatalytic conversion of CO2 to CH4 reaches 105.9 mu mol g(-1) h(-1), surpassing that of the majority of previously reported semiconductor photocatalysts like ZnFe2O4/CdS. This research offers a fresh perspective on the development of innovative heterojunction photocatalysts and broadens the utilization of ternary composite materials in CO2 photoreduction.