Efficient earth-abundant copper photocatalysis enabled by metal-arene interaction

被引：0
|
作者：
Deng, Chong [1 ,2 ]
Huang, Wenliang [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[2] Wanhua Chem Grp Co Ltd, Wanhua Res Inst, Yantai 264006, Peoples R China
来源：
CHEM | 2024年 / 10卷 / 09期
关键词：
D O I：
10.1016/j.chempr.2024.08.006
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this issue of Chem, Che et al. report a dinuclear copper(I) complex as an air-stable, efficient photocatalyst for C-C coupling reactions with unactivated aryl/alkyl halides. The photoinduced metal-metalto-ligand charge transfer excited state is capable of cleaving C-X bonds via halogen-atom transfer, while Cu-arene interaction is revealed to play a key role in enabling this photocatalysis.
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页数：3
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