A comparative study on the mechanical and flammability properties of aluminum hydroxide and hollow glass beads-filled polypropylene composites

被引:1
作者
Zheng, Yitao [1 ,2 ]
Gu, Fu [3 ,4 ,5 ]
Wang, Zheng [1 ]
Zhou, Yun [6 ]
Xu, Liqiang [7 ]
Hall, Philip [1 ,2 ]
机构
[1] Univ Nottingham Ningbo China, Dept Chem & Environm Engn, Room 437 Peter Mansfield Bldg,199 Taikang East Rd, Ningbo 315100, Peoples R China
[2] Nottingham Ningbo China Beacons Excellence Res & I, Ningbo, Peoples R China
[3] Zhejiang Univ, Polytech Inst, Ctr Engn Management, Hangzhou, Peoples R China
[4] Zhejiang Univ, Dept Ind & Syst Engn, Hangzhou, Peoples R China
[5] Zhejiang Univ, Natl Inst Innovat Management, Hangzhou, Peoples R China
[6] Ningbo Helong New Mat Co Ltd, Ningbo, Peoples R China
[7] Windey Energy Technol Grp Co Ltd, Hangzhou, Peoples R China
关键词
aluminum hydroxide; flame retardancy; hollow glass beads (HGB); mechanical properties; polypropylene; INTUMESCENT FLAME-RETARDANT; THERMAL-CONDUCTIVITY; MICROSPHERES; FIBER; FOAMS;
D O I
10.1002/vnl.22164
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Lightweight polypropylene (PP) composites with high flame retardancy and high thermal stability were required for automobile, electrical and electronic applications. Aluminum hydroxide (Al(OH)(3)) and two hollow glass beads (HGB) were selected as fillers for polypropylene composite fabrication. The incorporation of 10 wt% HGB (iM30K) into the PP matrix leads to a 3.5% density reduction, and 10 wt% Al(OH)(3) increased the density by 5.4%. The cone calorimeter test (CCT) showed the lowest PHRR of 536.6 kW/m(2) and peak smoke production rate of 0.061 m(2)/s was recorded for 10 wt% HGB (iM30K) loading. The formulation with 10 wt% Al(OH)(3) loading had the lowest flammability; however, the Al(OH)(3) content was not sufficient for a consistent flame-resistant performance. The incorporation of HGB and Al(OH)(3) resulted in an enhancement of both tensile and flexural modulus; however, it was observed that the tensile, flexural, and impact strengths exhibited a decrement with an increase in the concentration of HGB or Al(OH)(3). Moreover, the thermogravimetric analysis (TGA) results indicated that at the same filler content, HGB (S60HS) filled PP composites have the highest thermal stability among the prepared composites.
引用
收藏
页码:182 / 198
页数:17
相关论文
共 38 条
[1]   A flammability study of aluminium hydroxide (ATH) and ammonium polyphosphate (APP) used with hemp/epoxy composites [J].
Basnayake, Asanka P. ;
Hidalgo, Juan P. ;
Heitzmann, Michael T. .
CONSTRUCTION AND BUILDING MATERIALS, 2021, 304
[2]   Flame retardant polypropylene reinforced with natural additives [J].
Bazan, Patrycja ;
Salasi, Kamila ;
Kuciel, Stanislaw .
INDUSTRIAL CROPS AND PRODUCTS, 2021, 164
[3]   Flame retardancy of hollow glass microsphere/rigid polyurethane foams in the presence of expandable graphite [J].
Bian, Xiang-Cheng ;
Tang, Jian-Hua ;
Li, Zhong-Ming .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 109 (03) :1935-1943
[4]   Influence of interfacial interactions on the mechanical behavior of hybrid composites of polypropylene / short glass fibers / hollow glass beads [J].
Carvalho, Gustavo B. ;
Canevarolo Jr, Sebastiao, V ;
Sousa, Jose Alexandrino .
POLYMER TESTING, 2020, 85
[5]   Brominated flame retardants in the Arctic environment - trends and new candidates [J].
de Wit, Cynthia A. ;
Herzke, Dorte ;
Vorkamp, Katrin .
SCIENCE OF THE TOTAL ENVIRONMENT, 2010, 408 (15) :2885-2918
[6]   Synergistic effect of aluminum trihydrate and zirconium hydroxide nanoparticles on mechanical properties, flammability, and thermal degradation of polyester/jute fiber composite [J].
Ejaz, Mohsin ;
Azad, Muhammad Muzammil ;
Shah, Atta Ur Rehman ;
Afaq, S. Kamran ;
Song, Jung-il .
CELLULOSE, 2022, 29 (03) :1775-1790
[7]   Influence of coupling agents in the preparation of polypropylene composites reinforced with recycled fibers [J].
Franco-Marques, E. ;
Mendez, J. A. ;
Pelach, M. A. ;
Vilaseca, F. ;
Bayer, J. ;
Mutje, P. .
CHEMICAL ENGINEERING JOURNAL, 2011, 166 (03) :1170-1178
[8]   High specific strength hybrid polypropylene composites using carbon fibre and hollow glass microspheres: Development, characterization and comparison with empirical models [J].
Gogoi, Rupam ;
Manik, Gaurav ;
Arun, Byravan .
COMPOSITES PART B-ENGINEERING, 2019, 173
[9]   Ultrastrong, flexible and lightweight anisotropic polypropylene foams with superior flame retardancy [J].
Huang, Pengke ;
Wu, Minghui ;
Pang, Yongyan ;
Shen, Bin ;
Wu, Fei ;
Lan, Xiaoqin ;
Luo, Haibin ;
Zheng, Wenge .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2019, 116 :180-186
[10]   Polypropylene/glass fibre 3D-textile reinforced composites for automotive applications [J].
Hufenbach, W. ;
Boehm, R. ;
Thieme, M. ;
Winkler, A. ;
Maeder, E. ;
Rausch, J. ;
Schade, M. .
MATERIALS & DESIGN, 2011, 32 (03) :1468-1476