Rheological Equivalent Circuit Model Using Electrochemical Impedance Analysis

被引:1
作者
Choi, Hwan Woo [1 ]
Song, Young Seok [1 ]
机构
[1] Dankook Univ, Dept Fiber Convergence Mat Engn, Yongin 16890, Gyeonggi Do, South Korea
基金
新加坡国家研究基金会;
关键词
Cole-Cole plot; complex viscosity; electrochemical impedance spectroscopy (EIS); equivalent circuit; rheology; COMPLEX VISCOSITY; LEAST-SQUARES; BEHAVIOR; MODULUS;
D O I
10.1002/mats.202400069
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This study introduces a rheological equivalent circuit model inspired by electrochemical impedance spectroscopy (EIS) to analyze complex viscosity data. By exploiting the similarity between the Cole-Cole plot in rheology and the Nyquist plot in EIS, the study adopts circuit fitting methodologies to interpret rheological behavior of various polymers. The model employs redefined electrochemical elements, including dashpots, springs, rheological constant phase elements, and Warburg elements, to capture both linear and non-linear responses. This approach offers both analytical and predictive capabilities, providing new insights into material composition. This study introduces a rheological equivalent circuit model inspired by electrochemical impedance spectroscopy to analyze complex viscosity data. Circuit fitting methodologies are adopted to interpret rheological behavior of various polymers. The model employs redefined electrochemical elements to capture both linear and non-linear responses, offering analytical and predictive capabilities for understanding material composition and behavior. image
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页数:9
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