NITRIC OXIDE AND NITRITE REDUCTION BY METALLOENZYMES

被引:0
作者
Silaghi-Dumitrescu, Radu [1 ]
机构
[1] Univ Babes Bolyai, Dept Chem & Chem Engn, RO-400028 Cluj Napoca, Romania
基金
俄罗斯基础研究基金会;
关键词
nitrite reductase; nitric oxide reductase; linkage isomerism; density functional calculations; heme; PHTHALOCYANINE CATALYZED REDUCTION; ELECTRONIC-STRUCTURE; MOORELLA-THERMOACETICA; CYTOCHROME P450NOR; CRYSTAL-STRUCTURES; COMPLEXES; HEME; MECHANISM; KINETICS; BINDING;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Recent computational results from our group are reviewed on the mechanisms of enzymatic nitrite reduction to nitric oxide or ammonia, as well as nitric oxide reduction to nitrous oxide or ammonia, with sonic consideration for the electronic structures of electromeric species such as metal-nitric oxide adducts. Metal centers discussed include heme b, heme d(1), heme c, non-heme diiron, and copper.
引用
收藏
页码:513 / 522
页数:10
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