Porphyrin-silver acetylide cluster catalysts with dual active sites for the electrochemical reduction of CO2

被引：0

作者：

Curet, Leonard ^{[1
]}

Foix, Dominique ^{[1
]}

Palomares, Emilio ^{[2
,3
]}

Billon, Laurent ^{[1
]}

Viterisi, Aurelien ^{[1
]}

机构：

[1] Univ Pau & Pays Adour, CNRS, IPREM, E2S UPPA,UMR 5254,Technopole Helioparc, 2 Ave President Pierre Angot, F-64053 Pau 09, France

[2] Inst Chem Res Catalonia ICIQ, Avda Paisos Catalans 16, Tarragona 43007, Spain

[3] ICREA, Passeig Lluis Companys 28, E-08010 Barcelona, Spain

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 74期

关键词：

D O I：

10.1039/d4cc03836c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-step synthesis of porphyrin-silver acetylide clusters from tetra alkyne-substituted porphyrin is described. The solid-state properties of three 2D-like compounds were fully characterised using XPS and XRD while their catalytic properties under CO2 electroreduction reaction conditions were assessed and their faradaic efficiency quantified.

引用

页码：10168 / 10171

页数：4

共 50 条

[1] Metal Cluster Catalysts for Electrochemical CO2 Reduction
Dinh, Khac Huy
Menisa, Leta Takele
Warkentin, Hugh
Nguyen, Tu N.
Dinh, Cao-Thang
ACS CATALYSIS, 2025, 15 (07): : 5731 - 5759
[2] Active-Site Tailoring of Gold Cluster Catalysts for Electrochemical CO2 Reduction
Sun, Yongnan
Liu, Xu
Xiao, Kang
Zhu, Yan
Chen, Mingyang
ACS CATALYSIS, 2021, 11 (18) : 11551 - 11560
[3] Transforming active sites in nickel-nitrogen-carbon catalysts for efficient electrochemical CO2 reduction to CO
Daiyan, Rahman
Zhu, Xiaofeng
Tong, Zizheng
Gong, Lele
Razmjou, Amir
Liu, Ru-Shi
Xia, Zhenhai
Lu, Xunyu
Dai, Liming
Amal, Rose
NANO ENERGY, 2020, 78
[4] Water Facilitated Electrochemical Reduction of CO2 on Cobalt-Porphyrin Catalysts
Miyamoto, Kaito
Asahi, Ryoji
JOURNAL OF PHYSICAL CHEMISTRY C, 2019, 123 (15): : 9944 - 9948
[5] A review of the development of porphyrin-based catalysts for electrochemical CO2 reduction
Gu, Shengshen
Marianov, Aleksei N.
Lu, Tiandan
Zhong, Jing
CHEMICAL ENGINEERING JOURNAL, 2023, 470 (470)
[6] Molecular engineering for efficient and selective iron porphyrin catalysts for electrochemical reduction of CO2 to CO
Ambre, Ram B.
Daniel, Quentin
Fan, Ting
Chen, Hong
Zhang, Biaobiao
Wang, Lei
Ahlquist, Marten S. G.
Duan, Lele
Sun, Licheng
CHEMICAL COMMUNICATIONS, 2016, 52 (100) : 14478 - 14481
[7] Tailoring Metal-Porphyrin-Like Active Sites on Graphene to Improve the Efficiency and Selectivity of Electrochemical CO2 Reduction
Cheng, Mu-Jeng
Kwon, Youngkook
Head-Gordon, Martin
Bell, Alexis T.
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (37): : 21345 - 21352
[8] Bimetallic Copper-Silver Catalysts for the Electrochemical Reduction of CO2 to Ethanol
Robens, Elisabeth
Hecker, Burkhard
Kungl, Hans
Tempel, Hermann
Eichel, Ruediger-A.
ACS APPLIED ENERGY MATERIALS, 2023, 6 (14): : 7571 - 7577
[9] Electrochemical CO2 reduction of graphene single-atom/cluster catalysts
Gao, Yongze
Zhao, Mengdie
Jiang, Liyun
Yu, Qi
MOLECULAR CATALYSIS, 2024, 562
[10] CO2 or Carbonates - What is the Active Species in Electrochemical CO2 Reduction over Fe-Porphyrin?
Khakpour, Reza
Lindberg, Daniel
Laasonen, Kari
Busch, Michael
CHEMCATCHEM, 2023, 15 (06)

← 1 2 3 4 5 →