Heat Capacity of Solid Halide Eutectics and Their Enthalpy at Melting Point

被引:1
作者
Redkin, Alexander [1 ]
Korzun, Iraida [1 ]
Yaroslavtseva, Tatyana [2 ]
Reznitskikh, Olga [2 ]
Zaikov, Yuriy [1 ]
Kumkov, Sergeiy [3 ]
Kodintseva, Anna [1 ]
机构
[1] Russian Acad Sci, Inst High Temp Electrochem, Ural Branch, Ekaterinburg 620066, Russia
[2] Russian Acad Sci, Inst Solid State Chem, Ural Branch, Ekaterinburg 620108, Russia
[3] Russian Acad Sci, Inst Math & Mech, Ural Branch, Ekaterinburg 620108, Russia
来源
THERMO | 2023年 / 3卷 / 01期
关键词
alkali halides eutectics; heat capacity; enthalpy; melting temperature; CHLORIDE; FUSION; TECHNOLOGY; CRYSTALS; MIXTURE; SALTS;
D O I
10.3390/thermo3010007
中图分类号
O414.1 [热力学];
学科分类号
摘要
The isobaric heat capacity of solid eutectic mixtures LiCl-KCl-CsCl, LiBr-CsBr and LiBr-KBr-CsBr was investigated from room temperature up to melting point. The molar heat capacity of all mixtures under study was found to be close to the additive sum of that of pure salts. The heat accumulated up to melting temperature is directly dependent on the melting point.
引用
收藏
页码:96 / 103
页数:8
相关论文
共 24 条
  • [1] Atkinson K. E., 1989, INTRO NUMERICAL ANAL
  • [2] Enthalpy of fusion prediction for the economic optimisation of salt based latent heat thermal energy stores
    Badenhorst, Heinrich
    Bohmer, Thomas
    [J]. JOURNAL OF ENERGY STORAGE, 2018, 20 : 459 - 472
  • [3] Excess Heat Capacity in Liquid Binary Alkali-Fluoride Mixtures
    Beilmann, M.
    Benes, O.
    Capelli, E.
    Reuscher, V.
    Konings, R. J. M.
    Fanghaenel, Th.
    [J]. INORGANIC CHEMISTRY, 2013, 52 (05) : 2404 - 2411
  • [4] THE THERMAL PROPERTIES OF ALKALI HALIDE CRYSTALS .1. THE HEAT CAPACITY OF POTASSIUM CHLORIDE, POTASSIUM BROMIDE, POTASSIUM IODIDE AND SODIUM IODIDE BETWEEN 2.8-DEGREES-K AND 270-DEGREES-K
    BERG, WT
    MORRISON, JA
    [J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1957, 242 (1231): : 467 - 477
  • [5] Mainstreaming commercial CSP systems: A technology review
    Fernandez, Angel G.
    Gomez-Vidal, Judith
    Oro, Eduard
    Kruizenga, Alan
    Sole, Aran
    Cabeza, Luisa F.
    [J]. RENEWABLE ENERGY, 2019, 140 : 152 - 176
  • [6] Thermal characterization of solar salts from north of Chile and variations of their properties over time at high temperature
    Fernandez, Angel G.
    Veliz, Sussy
    Fuentealba, Edward
    Galleguillos, Hector
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2017, 128 (03) : 1241 - 1249
  • [7] A view and a review of the melting of alkali metal halide crystals - part 1. A melt model based on density and energy changes
    Galwey, AK
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2005, 82 (01) : 23 - 40
  • [8] Heat capacity of LaCl3,CeCl3,PrCl3,NdCl3,GdCl3,DyCl3
    GauneEscard, M
    Bogacz, A
    Rycerz, L
    Szczepaniak, W
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 235 (02) : 176 - 181
  • [9] Glushko V.P., 1982, Thermodynamic properties of individual substances. Reference book, V4
  • [10] Grimes W., 1966, ORNL-3913, P29