Modeling Rate Dependent Volume Change in Porous Electrodes in Lithium-Ion Batteries

被引:7
作者
Garrick, Taylor R. [1 ]
Fernandez, Miguel A. [1 ]
Koch, Brian J. [2 ]
Efimoff, Erin [1 ]
Jones, Matthew [1 ]
Mollah, Rafid [1 ]
Teel, Hunter [1 ,3 ]
Du, Xiaoniu [4 ]
Shimpalee, Sirivatch [3 ]
Choe, Song-Yul [4 ]
Subramanian, Venkat R. [5 ]
Siegel, Jason B. [6 ]
机构
[1] Gen Motors Global Tech Ctr, Global Electrificat & Battery Syst, Warren, MI 48092 USA
[2] Gen Motors Global Tech Ctr, Battery Mat & Syst Res, Warren, MI 48092 USA
[3] Univ South Carolina, Chem Engn, Columbia, SC 29208 USA
[4] Auburn Univ, Mech Engn, Auburn, AL 36849 USA
[5] Univ Texas Austin, Texas Mat Inst, Dept Mech Engn & Mat Sci Engn, Austin, TX 78712 USA
[6] Univ Michigan, Mech Engn, Ann Arbor, MI 48109 USA
关键词
batteries; -; lithium; electrochemical engineering; volume change; electric vehicle; intercalation; graphite; LINEAR-SWEEP VOLTAMMETRY; MULTI-REACTION MODEL; INTERCALATION ELECTRODES; OPTIMIZATION; PERFORMANCE; SIMULATION;
D O I
10.1149/1945-7111/ad6483
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Automotive manufacturers are working to improve individual cell, module, and overall pack design by increasing the performance, range, and durability, while reducing cost. One key piece to consider during the design process is the active material volume change, its linkage to the particle, electrode, and cell level volume changes, and the interplay with structural components in the rechargeable energy storage system. As the time from initial design to manufacture of electric vehicles decreases, design work needs to move to the virtual domain; therefore, a need for coupled electrochemical-mechanical models that take into account the active material volume change and the rate dependence of this volume change need to be considered. In this study, we illustrated the applicability of a coupled electrochemical-mechanical battery model considering multiple representative particles to capture experimentally measured rate dependent reversible volume change at the cell level through the use of an electrochemical-mechanical battery model that couples the particle, electrode, and cell level volume changes. By employing this coupled approach, the importance of considering multiple active material particle sizes representative of the distribution is demonstrated. The non-uniformity in utilization between two different size particles as well as the significant spatial non-uniformity in the radial direction of the larger particles is the primary driver of the rate dependent characteristics of the volume change at the electrode and cell level.
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页数:24
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  • [1] One-Step Non-Reactive Spray Drying Approach to Produce Silicon/Carbon Composite-Based Hierarchically Structured Supraparticles for Lithium-Ion Battery Anodes
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    Wassmer, Theresa
    Bade, Stefan
    Lyubina, Julia
    Wiggers, Hartmut
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    Segets, Doris
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2023, 170 (02)
  • [2] Electrochemical Performance of Mixed Redox-Active Organic Molecules in Redox Flow Batteries
    Amini, Kiana
    Jing, Yan
    Gao, Jinxu
    Sosa, Jordan D.
    Gordon, Roy G.
    Aziz, Michael J.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2023, 170 (12)
  • [3] Modeling Reversible Expansion of Porous Electrodes in Si/NMC Cells within the Framework of Multi-Species, Multi-Reaction Theory
    Arisetty, Srikanth
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    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2022, 169 (11)
  • [4] Slow Current or Potential Scanning of Battery Porous Electrodes: Generalized Perturbation Solution and the Merits of Sinusoidal Current Cycling
    Baker, Daniel R.
    Verbrugge, Mark W.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2021, 168 (05)
  • [5] Modeling Overcharge at Graphite Electrodes: Plating and Dissolution of Lithium
    Baker, Daniel R.
    Verbrugge, Mark W.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 167 (01)
  • [6] Multi-Species, Multi-Reaction Model for Porous Intercalation Electrodes: Part II. Model-Experiment Comparisons for Linear-Sweep Voltammetry of Spinel Lithium Manganese Oxide Electrodes
    Baker, Daniel R.
    Verbrugge, Mark W.
    Gu, Wentian
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 166 (04) : A521 - A531
  • [7] Multi-Species, Multi-Reaction Model for Porous Intercalation Electrodes: Part I. Model Formulation and a Perturbation Solution for Low-Scan-Rate, Linear-Sweep Voltammetry of a Spinel Lithium Manganese Oxide Electrode
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    Verbrugge, Mark W.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2018, 165 (16) : A3952 - A3964
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    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2024, 171 (03)