Selective separation of CO2/CH4 gases by metal-organic framework-based composites

被引:12
作者
Yan, Xiao-Wei [1 ]
Bigdeli, Fahime [2 ]
Abbasi-Azad, Mahsa [2 ]
Wang, Su-Juan [1 ]
Morsali, Ali [2 ]
机构
[1] Hezhou Univ, Sch Food & Bioengn, Guangxi Key Lab Hlth Care Food Sci & Technol, 18 West Ring Rd, Hezhou 542899, Guangxi, Peoples R China
[2] Tarbiat Modares Univ, Fac Sci, Dept Chem, POB 14115-175, Tehran, Iran
关键词
Metal-organic framework; Composite; CO; 2; /CH; 4; separation; MIXED-MATRIX MEMBRANES; METHANE CAPTURE; CO2; SEPARATION; IONIC LIQUIDS; CU-BTC; PERFORMANCE; ADSORPTION; CO2/N-2; ZIF-8; IMPROVE;
D O I
10.1016/j.ccr.2024.216126
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In natural gas refining, separation of CO2 2 from methane is an important research issue, because CO2 2 wastes natural gas energy and causes pipeline corrosion. Compared to common technologies, adsorption-based processes are noteworthy for gas separation because they are inexpensive and have high efficiency. A type of composite consists of a polymer matrix and organic or inorganic fillers. By integrating metal-organic frameworks (MOFs) into the polymer matrix, composites with a defect-free surface are formed because organic linkers in MOFs can provide a suitable combination with organic polymers to form a proper membrane for separation of the CO2/CH4 2 /CH 4 gases. Here, an attempt has been made to investigate various types of composites based on their nature, the impact of functional groups in the structure of MOFs, as well as two-dimensional MOFs on the separation efficiency of CO2 2 and CH4 4 gases.
引用
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页数:26
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