Improving geopolymer concrete performance with hazardous solid waste phosphogypsum

Recycling the hazardous solid waste phosphogypsum (PG) in concrete is a popular trend. However, the inherent properties of PG used alone in concrete tend to limit the strength of the concrete. In this study, PG was used as a precursor for the production of phosphogypsum-based geopolymer concrete (PGC), which effectively improved the performance of geopolymer concrete by utilising the synergistic effect of different solid wastes in geopolymer concrete. The effects of PG content (0, 10, and 20 %) and alkali modulus (0.8, 0.95, 1.1, and 1.25) on the axial compressive properties and resistance to chloride penetration of PGC were investigated. The results show that 10 % PG improved the properties of geopolymer concrete the most, with a maximum increase in axial compressive strength of 17 %. Due to the addition of SO42-, the PG content also affected the optimal alkaline modulus of PGCs. Chemical composition and micro- structural analyses revealed that the promotion of the geopolymer reaction by PG is crucial for PGC performance enhancement. In addition, leaching tests and carbon emission assessment, confirmed that PGCs are an environmentally friendly option. Based on the analysis of axial compression behaviour, resistance to chloride ion permeability and environmental impact, PGC with 10 % PG content and 1.1 alkali modulus is an environmentally friendly alternative to conventional concrete. This study shows that hazardous solid waste PG can improve the performance of geopolymer concrete and create a new type of solid waste concrete.