The employment of a core catcher is instrumental in enhancing the safety of nuclear power facilities in the event of severe accidents, with sacrificial materials serving as fundamental constituents. Currently, cement-based sacrificial materials are prevalently utilized due to their straightforward construction methodologies and economical production costs. These materials are designed to withstand significant impact loads arising from the descent of core melt during severe accidents. To augment the impact resilience of sacrificial materials, a novel functional ultra-high performance concrete (FUHPC) incorporating barium ferrite has been developed. Using the Modified Andreasen and Andersen particle packing model to determine the initial mixture of FUHPC, and the impact of barium ferrite on the mechanical and thermal properties of FUHPC was systematically evaluated. Furthermore, the influence of barium ferrite on the FUHPC's microstructure was examined with mercury intrusion porosity and scanning electron microscopy techniques. The findings indicate: (1) Optimal barium ferrite incorporation led to a decrease in the porosity and the threshold pore diameter of FUHPC; (2) The flexural and compressive strengths, as well as the elastic modulus of FUHPC, were found to increase within the ranges of 4.41%-17.50 %, 2.88%-22.91 %, and 5.80%-15.06 %, respectively, as a result of suitable barium ferrite additions; (3) At a barium ferrite concentration of 2 vol%, the chloride migration coefficient of FUHPC was reduced by 21.43 %; (4) The presence of barium ferrite enhanced the impact performance of FUHPC, with a 21.38 % increase in impact resistance noted at a barium ferrite content of 2 vol%; (5) In high-temperature scenarios, the formation of channels from melted polypropylene fibers served to mitigate the spalling of FUHPC; (6) Upon considering the effects of barium ferrite on both room temperature and elevated temperature performance, as well as on microstructural characteristics, the optimal barium ferrite content was determined to be 2 vol%.
