Enhancing Polylactic Acid Properties with Graphene Nanoplatelets and Carbon Black Nanoparticles: A Study of the Electrical and Mechanical Characterization of 3D-Printed and Injection-Molded Samples

被引:1
作者
Giner-Grau, Salvador [1 ]
Lazaro-Hdez, Carlos [2 ]
Pascual, Javier [1 ]
Fenollar, Octavio [2 ]
Boronat, Teodomiro [2 ]
机构
[1] Text Ind Res Assoc AITEX, Plaza Emilio Sala 1, Alcoy 03801, Spain
[2] Univ Politecn Valencia UPV, Inst Univ Invest Tecnol Mat IUITM, Plaza Ferrandiz & Carbonell 1, Alcoy 03801, Spain
关键词
PLA; nanoadditives; 3D printing; injection molding; POLY(LACTIC ACID); PERFORMANCE; PLA; FABRICATION; PARAMETERS; NANOTUBES; BEHAVIOR;
D O I
10.3390/polym16172449
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This study investigates the enhancement of polylactic acid (PLA) properties through the incorporation of graphene nanoplatelets (GNPs) and carbon black (CB) for applications in 3D printing and injection molding. The research reveals that GNPs and CB improve the electrical conductivity of PLA, although conductivity remains within the insulating range, even with up to 10% wt of nanoadditives. Mechanical characterization shows that nanoparticle addition decreases tensile strength due to stress concentration effects, while dispersants like polyethylene glycol enhance ductility and flexibility. This study compares the properties of materials processed by injection molding and 3D printing, noting that injection molding yields isotropic properties, resulting in better mechanical properties. Thermal analysis indicates that GNPs and CB influence the crystallization behavior of PLA with small changes in the melting behavior. Dynamic Mechanical Thermal Analysis (DMTA) results show how the glass transition temperature and crystallization behavior fluctuate. Overall, the incorporation of nanoadditives into PLA holds potential for enhanced performance in specific applications, though achieving optimal conductivity, mechanical strength, and thermal properties requires careful optimization of nanoparticle type, concentration, and dispersion methods.
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页数:17
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共 70 条
  • [1] Study of the Influence of the Reprocessing Cycles on the Final Properties of Polylactide Pieces Obtained by Injection Molding
    Aguero, Angel
    del Carmen Morcillo, Maria
    Quiles-Carrillo, Luis
    Balart, Rafael
    Boronat, Teodomiro
    Lascano, Diego
    Torres-Giner, Sergio
    Fenollar, Octavio
    [J]. POLYMERS, 2019, 11 (12)
  • [2] Interlayer bonding has bulk-material strength in extrusion additive manufacturing: New understanding of anisotropy
    Allum, James
    Moetazedian, Amirpasha
    Gleadall, Andrew
    Silberschmidt, Vadim V.
    [J]. ADDITIVE MANUFACTURING, 2020, 34 (34)
  • [3] A rheological approach to 3D printing of plasma protein based doughs
    Alvarez-Castillo, Estefania
    Oliveira, Sonia
    Bengoechea, Carlos
    Sousa, Isabel
    Raymundo, Anabela
    Guerrero, Antonio
    [J]. JOURNAL OF FOOD ENGINEERING, 2021, 288
  • [4] [Anonymous], 2010, ISO 179-1:2010, V22
  • [5] [Anonymous], 2012, PlasticsDetermination of Tensile Properties. Part 2: Test Conditions for Moulding and Extrusion Plastics
  • [6] [Anonymous], 2003, 8682003 ISO
  • [7] Biodegradable electrospun PLA-PHB fibers plasticized with oligomeric lactic acid
    Arrieta, Marina P.
    Perdiguero, Miguel
    Fiori, Stefano
    Maria Kenny, Jose
    Peponi, Laura
    [J]. POLYMER DEGRADATION AND STABILITY, 2020, 179
  • [8] Reasons and remedies for the agglomeration of multilayered graphene and carbon nanotubes in polymers
    Atif, Rasheed
    Inam, Fawad
    [J]. BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2016, 7 : 1174 - 1196
  • [9] Biodegradable poly(lactic acid) nanocomposites reinforced and toughened by carbon nanotubes/clay hybrids
    Bai, Tiantian
    Zhu, Bo
    Liu, Hu
    Wang, Yaming
    Song, Gang
    Liu, Chuntai
    Shen, Changyu
    [J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2020, 151 : 628 - 634
  • [10] Effect of Plasticization/Annealing on Thermal, Dynamic Mechanical, and Rheological Properties of Poly(Lactic Acid)
    Benkraled, Lina
    Zennaki, Assia
    Zair, Latifa
    Arabeche, Khadidja
    Berrayah, Abdelkader
    Barrera, Ana
    Bouberka, Zohra
    Maschke, Ulrich
    [J]. POLYMERS, 2024, 16 (07)