Enhancing Polylactic Acid Properties with Graphene Nanoplatelets and Carbon Black Nanoparticles: A Study of the Electrical and Mechanical Characterization of 3D-Printed and Injection-Molded Samples

被引:2
作者
Giner-Grau, Salvador [1 ]
Lazaro-Hdez, Carlos [2 ]
Pascual, Javier [1 ]
Fenollar, Octavio [2 ]
Boronat, Teodomiro [2 ]
机构
[1] Text Ind Res Assoc AITEX, Plaza Emilio Sala 1, Alcoy 03801, Spain
[2] Univ Politecn Valencia UPV, Inst Univ Invest Tecnol Mat IUITM, Plaza Ferrandiz & Carbonell 1, Alcoy 03801, Spain
关键词
PLA; nanoadditives; 3D printing; injection molding; POLY(LACTIC ACID); PERFORMANCE; PLA; FABRICATION; PARAMETERS; NANOTUBES; BEHAVIOR;
D O I
10.3390/polym16172449
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This study investigates the enhancement of polylactic acid (PLA) properties through the incorporation of graphene nanoplatelets (GNPs) and carbon black (CB) for applications in 3D printing and injection molding. The research reveals that GNPs and CB improve the electrical conductivity of PLA, although conductivity remains within the insulating range, even with up to 10% wt of nanoadditives. Mechanical characterization shows that nanoparticle addition decreases tensile strength due to stress concentration effects, while dispersants like polyethylene glycol enhance ductility and flexibility. This study compares the properties of materials processed by injection molding and 3D printing, noting that injection molding yields isotropic properties, resulting in better mechanical properties. Thermal analysis indicates that GNPs and CB influence the crystallization behavior of PLA with small changes in the melting behavior. Dynamic Mechanical Thermal Analysis (DMTA) results show how the glass transition temperature and crystallization behavior fluctuate. Overall, the incorporation of nanoadditives into PLA holds potential for enhanced performance in specific applications, though achieving optimal conductivity, mechanical strength, and thermal properties requires careful optimization of nanoparticle type, concentration, and dispersion methods.
引用
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页数:17
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