Crystal-to-crystal polymorphic phase transition in a cocrystal accompanied by expansion and surface wettability change

被引:2
|
作者
Saikia, Plabon [1 ]
Gupta, Poonam [1 ]
Nath, Tridib R. [2 ]
Nath, Naba K. [1 ]
机构
[1] Natl Inst Technol, Dept Chem & Biol Sci, Shillong, Meghalaya, India
[2] Tezpur Univ, Sophisticated Analyt Instrumentat Ctr, Tezpur 784001, Assam, India
关键词
MOLECULAR-CRYSTALS; PHARMACEUTICAL COCRYSTALS; BEHAVIOR; FORMS; DYE;
D O I
10.1039/d4ce00407h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, cocrystallization of n-propylparaben and a ditopic bipyridine-based azine derivative in a 2 : 1 stoichiometric ratio was carried out. The resulting single crystals of the cocrystal displayed crystal-to-crystal polymorphic phase transformation on heating. The phase transformation is associated with naked-eye visible expansion and cracking of the single crystals. The two polymorphs are distinct in their surface wettability. Cocrystal of n-propylparaben and a bipyridine-based azine derivative exhibit heat-induced crystal-to-crystal polymorphic phase transition accompanied by expansion and cracking of the single crystals with distinct wettability properties.
引用
收藏
页码:4259 / 4263
页数:5
相关论文
共 50 条
  • [31] Guest-induced crystal-to-crystal expansion and contraction of a 3-D porous coordination polymer
    Bloch, Witold M.
    Sumby, Christopher J.
    CHEMICAL COMMUNICATIONS, 2012, 48 (19) : 2534 - 2536
  • [32] Kinetics for Inhibited Polymorphic Transition of HMX Crystal after Strong Surface Confinement
    Gong, Feiyan
    Yang, Zhijian
    Qjan, Wen
    Liu, Yu
    Zhang, Jianhu
    Ding, Ling
    Lin, Congmei
    Zeng, Chengcheng
    Yan, Qilong
    JOURNAL OF PHYSICAL CHEMISTRY C, 2019, 123 (17): : 11011 - 11019
  • [33] Crystal surface defects as possible origins of cocrystal dissociation
    Eddleston, Mark D.
    Chow, Ernest H. H.
    Bucar, Dejan-Kresimir
    Thakuria, Ranjit
    CRYSTENGCOMM, 2022, 24 (28) : 5031 - 5035
  • [34] Preferential enrichment - Crystal structure and polymorphic transition
    Tamura, R
    Takahashi, H
    Ushio, T
    NIPPON KAGAKU KAISHI, 2001, (02) : 71 - 82
  • [35] X-ray powder and single crystal diffraction study of the reversible crystal-to-crystal transition of hexanuclear copper(I) benzoate
    Filatov, Alexander S.
    Hietsoi, Oleksandr
    Petrukhina, Marina A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [36] POLYMORPHIC TRANSITION IN THE SINGLE-CRYSTAL OF HAFNIUM
    RUKHLYADA, NY
    TREFILOV, AG
    SHISHKIN, BB
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 3 FIZIKA ASTRONOMIYA, 1979, 20 (02): : 70 - 72
  • [37] A Screening Approach for the Discovery of Mechanochromic Gold(I) Isocyanide Complexes with Crystal-to-Crystal Phase Transitions
    Seki, Tomohiro
    Takamatsu, Yuki
    Ito, Hajime
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (19) : 6252 - 6260
  • [38] Jumping Crystals of Pyrene Tweezers: Crystal-to-Crystal Transition Involving π/π-to-CH/π Assembly Mode Switching
    Shibuya, Yoshiki
    Itoh, Yoshimitsu
    Aida, Takuzo
    CHEMISTRY-AN ASIAN JOURNAL, 2017, 12 (07) : 811 - 815
  • [39] Intimate relationship between structural change in crystal lattice and morphological change during the phase transition of polymer crystal
    Tashiro, Kohji
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 234
  • [40] SEARCH FOR A PRECURSOR CRYSTAL-TO-CRYSTAL PHASE-TRANSITION TO AMORPHIZATION IN ALPHA-GEO(2) AND ALPHA-ALPO(4) UNDER PRESSURE
    SOMAYAZULU, MS
    GARG, N
    SHARMA, SM
    SIKKA, SK
    PRAMANA-JOURNAL OF PHYSICS, 1994, 43 (01): : 1 - 9