Unleashing the power of non-edible oil seeds of Ipomoea cairica for cleaner and sustainable biodiesel production using green Molybdenum Oxide (MoO3) nano catalyst

被引:21
作者
Chaudhry, Bisha [1 ]
Ahmad, Mushtaq [1 ,2 ]
Munir, Mamoona [1 ,3 ]
Ramadan, Mohamed Fawzy [4 ]
Munir, Mumna [1 ]
Mussagy, Cassamo Ussemane [5 ]
Faisal, Shah [6 ]
Abdellatief, Tamer M. M. [7 ,8 ]
Mustafa, Ahmad [9 ]
机构
[1] Quaid I Azam Univ, Dept Plant Sci, Biofuel Lab, Islamabad, Pakistan
[2] Neijiang Normal Univ, Coll Life Sci, Neijiang 641000, Sichuan, Peoples R China
[3] Rawalpindi Women Univ, Dept Bot, Satellite Town, Rawalpindi, Pakistan
[4] Umm Al Qura Univ, Fac Appl Med Sci, Dept Clin Nutr, Mecca, Saudi Arabia
[5] Pontificia Univ Catolica Valparaiso, Escuela Agron, Fac Ciencias Agron & Alimentos, Valparaiso, Chile
[6] Chengdu Univ, Sch Architecture & Civil Engn, Dept Environm Engn, Chengdu 610106, Peoples R China
[7] Univ Sharjah, Sustainable Energy & Power Syst Res Ctr, RISE, POB 27272, Sharjah, U Arab Emirates
[8] Minia Univ, Fac Engn, Chem Engn Dept, El Minia 61519, Egypt
[9] October Univ Modern Sci & Arts MSA, Fac Engn, Giza, Egypt
关键词
Non-edible oil seeds; Cleaner energy source; Sustainable biodiesel production; Ipomea cairica; Green revolution; COLD FLOW PROPERTIES; FISH-OIL; OPTIMIZATION; FUEL; COMPATIBILITY; WATER; DEGRADATION; CONVERSION;
D O I
10.1016/j.seta.2024.103781
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This research aims to conduct a thorough analysis of the novel and cost-effective use of Ipomoea cairica L. seeds as a potential feedstock for green energy technologies. Ipomoea cairica L. seeds (42 % oil, 0.67 % free fatty acid content) were used as a promising source for producing sustainable biodiesel using novel green Molybdenum Oxide (MoO3) nanocatalyst. The Ipomoea cairica seeds utilized in this study serve a dual purpose: they provide feedstock for the future energy mix, and their seed shells (considered waste) are used as a starting material for synthesizing green nanocatalysts. The highest biodiesel yield of 95 % was achieved under optimal reaction conditions of 1:15 oil to methanol molar ratio, 50 degrees C, 120 min, and 0.4 (wt.%) catalyst loading. In order to evaluate the quality and characteristics of the resultant biodiesel and synthesized nanocatalyst, a detailed examination was conducted utilizing analytical techniques such EDX, XRD, FTIR, SEM, NMR (1H, 13C) and GC-MS analysis. The phytofabricated nanocatalyst unveils highest recyclability (up to 5 cycles), reactivity, stability and efficiency during transesterification operations. The produced biodiesel was also optimized using response surface methodology (Box-Behnken Design). When compared to conventional diesel, the biodiesel made from Ipomoea cairica L. seed oil showed better oxidative stability and reduced viscosity, suggesting that it might be a viable replacement for conventional fuel without compromising engine performance. Moreover, using untamed, uncultivated, and non-edible seed plants to produce biodiesel presents a chance to move toward a more sustainable and environmentally friendly energy plan.
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页数:14
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