共 2 条
Characteristics of nutrients and heavy metals release from sewage sludge biochar produced by industrial-scale pyrolysis in the aquatic environment and its potential as a slow-release fertilizer and adsorbent
被引:1
|作者:
Wei, Chunzhong
[1
]
Liu, Liheng
[2
,3
,4
]
Yi, Wei
[2
]
Yu, Ronghao
[2
]
Xu, Yufeng
[2
,3
,4
]
Zeng, Si
[1
]
机构:
[1] Guangxi Beitou Environm Protect & Water Grp Co Ltd, Nanning 530025, Peoples R China
[2] Guilin Univ Technol, Coll Environm Sci & Engn, Guilin 541006, Peoples R China
[3] Guilin Univ Technol, Guangxi Key Lab Environm Pollut Control Theory & T, Guilin 541006, Peoples R China
[4] Guilin Univ Technol, Collaborat Innovat Ctr Water Pollut Control & Wate, Guilin 541006, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Sewage sludge biochar;
Industrial-scale pyrolysis;
Nutrients and heavy metals;
Release characteristics;
Potential for application;
ION;
KINETICS;
PHOSPHORUS;
ADSORPTION;
BEHAVIOR;
MANURE;
D O I:
10.1016/j.jenvman.2024.121871
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
To assess the application potential of sewage sludge biochar produced by industrial-scale pyrolysis (ISB), the release characteristics of nutrients (NH4+, PO43-, K, Ca, Mg and Fe) and heavy metals (Mn, Cu, Zn, Pb, Ni and Cr) were investigated. Their release amounts increased with decreasing initial pH and increasing solid-liquid ratios (RS-L) and temperature. The release types of NH4+, K, Mg, and Mn were diffusion/dissolution, while those of Cu, Zn, Pb, Ni, and Cr were diffusion/resorption. The release types of PO43- and Ca varied with initial pH and R S-L , respectively. The chemical actions played dominant roles in their release, while particle surface diffusion and liquid film diffusion determined the rates of diffusion and resorption phases, respectively. The release of NH 4 + , PO43-, K, Ca, Mg, Mn and Zn was a non-interfering, spontaneous (except PO43-), endothermic, and elevated randomness process. The release efficiency of NH4+, PO43- and K met the Chinese standard for slow-release fertilizers, while the total risk of ISB was low. The eutrophication and potential ecological risks of ISB were acceptable when the dose was less than 3 g L-1 and the initial pH was no lower than 3. In conclusion, ISB had potential as a slow-release fertilizer and adsorbent.
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