Characteristics of nutrients and heavy metals release from sewage sludge biochar produced by industrial-scale pyrolysis in the aquatic environment and its potential as a slow-release fertilizer and adsorbent

被引:1
|
作者
Wei, Chunzhong [1 ]
Liu, Liheng [2 ,3 ,4 ]
Yi, Wei [2 ]
Yu, Ronghao [2 ]
Xu, Yufeng [2 ,3 ,4 ]
Zeng, Si [1 ]
机构
[1] Guangxi Beitou Environm Protect & Water Grp Co Ltd, Nanning 530025, Peoples R China
[2] Guilin Univ Technol, Coll Environm Sci & Engn, Guilin 541006, Peoples R China
[3] Guilin Univ Technol, Guangxi Key Lab Environm Pollut Control Theory & T, Guilin 541006, Peoples R China
[4] Guilin Univ Technol, Collaborat Innovat Ctr Water Pollut Control & Wate, Guilin 541006, Peoples R China
基金
中国国家自然科学基金;
关键词
Sewage sludge biochar; Industrial-scale pyrolysis; Nutrients and heavy metals; Release characteristics; Potential for application; ION; KINETICS; PHOSPHORUS; ADSORPTION; BEHAVIOR; MANURE;
D O I
10.1016/j.jenvman.2024.121871
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
To assess the application potential of sewage sludge biochar produced by industrial-scale pyrolysis (ISB), the release characteristics of nutrients (NH4+, PO43-, K, Ca, Mg and Fe) and heavy metals (Mn, Cu, Zn, Pb, Ni and Cr) were investigated. Their release amounts increased with decreasing initial pH and increasing solid-liquid ratios (RS-L) and temperature. The release types of NH4+, K, Mg, and Mn were diffusion/dissolution, while those of Cu, Zn, Pb, Ni, and Cr were diffusion/resorption. The release types of PO43- and Ca varied with initial pH and R S-L , respectively. The chemical actions played dominant roles in their release, while particle surface diffusion and liquid film diffusion determined the rates of diffusion and resorption phases, respectively. The release of NH 4 + , PO43-, K, Ca, Mg, Mn and Zn was a non-interfering, spontaneous (except PO43-), endothermic, and elevated randomness process. The release efficiency of NH4+, PO43- and K met the Chinese standard for slow-release fertilizers, while the total risk of ISB was low. The eutrophication and potential ecological risks of ISB were acceptable when the dose was less than 3 g L-1 and the initial pH was no lower than 3. In conclusion, ISB had potential as a slow-release fertilizer and adsorbent.
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页数:10
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