Investigation of MnCo2O4 Spinel Loaded onto Porous γ-Al2O3 as an Electrocatalyst for Water-Splitting Performance

被引:3
作者
Jamshidi, Fariba [1 ]
Gholivand, Mohammad-Bagher [1 ]
机构
[1] Razi Univ, Fac Chem, Dept Analyt Chem, Kermanshah 6714967346, Iran
来源
ACS APPLIED ENGINEERING MATERIALS | 2024年 / 2卷 / 01期
关键词
energy; water splitting; HER; OER; gamma-Al2O3; MnCo2O4; nanoparticles; OXYGEN EVOLUTION REACTION; BIFUNCTIONAL CATALYSTS; MAGNETIC-PROPERTIES; ALUMINA POWDER; EFFICIENT; NANOSHEETS; SUPERIOR; RGO;
D O I
10.1021/acsaenm.3c00641
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electrocatalytic water splitting is one of the most effective ways to produce hydrogen as a clean energy carrier for the future of global energy provision that enables the production of energy to become independent of fossil fuels. In this work, we present a two-step hydrothermal method as a synthesis approach for the preparation of MnCo2O4 nanoparticles loaded on porous gamma-Al2O3 (Al2O3/Mn-Co). This composite was characterized by different techniques, and then it was used as an electrode material to create an electrocatalyst for water splitting with great performance. This composite exhibited enhanced electrocatalytic activity requiring an overpotential of similar to 113 and similar to 270 mV at the current density of 10 mA cm(-2) for the reactions of HER and OER, respectively, and a comparatively low cell voltage (similar to 1.57 V) for overall water splitting. The Tafel slopes for HER and OER were 74 and 63 mV dec(-1) and also show a long-range stability of 14 h. The present results would exhibit a new chance to design and develop a multicomponent electrocatalyst for the overall water electrolysis.
引用
收藏
页码:104 / 115
页数:12
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