Effect of borosilicate residue as flame retardant and reinforcement filler in polypropylene/natural fiber composites

被引:0
作者
Poletto, Murillo Ricardo Lombardo [1 ]
Callegari, Bruna [1 ]
Ferreira, Eduardo Bellini [1 ]
Branciforti, Marcia Cristina [1 ]
机构
[1] Univ Sao Paulo, Sao Carlos Sch Engn, Dept Mat Engn, Ave Trabalhador San Carlense 400, BR-13566 590 Sao Carlos, Brazil
关键词
composite; flame retardant; natural fiber; polypropylene; MECHANICAL-PROPERTIES; THERMAL-PROPERTIES; WOOD FLOUR; FLAMMABILITY; FIRE; ACID;
D O I
10.1002/app.56166
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This study evaluated the influence of adding borosilicate residue (BS) as a flame retardant in polypropylene (PP) and natural fiber composites. The natural fibers used in this study come from the residue of the carpet industry, which is composed of PP and jute fibers (JT), while the PP used as the polymer matrix is postindustrial recycled material. The composites were produced by corotational twin-screw extrusion and injection molding to obtain the test specimens. A coating process was carried out to add the water-soluble fraction of BS to the surface of the compositions that did not receive it through incorporation during processing. To characterize the composites, flammability tests, thermogravimetric analysis (TGA), tensile strength test, and morphological analysis by scanning electron microscope (SEM) were performed. The addition of only 2 wt% BS content induces an increase in thermal stability of 32 and 109 degrees C for composites with and without natural fibers, respectively. The addiction of 20 wt% BS elevates the elastic modulus up to 27% of the composites with and without natural fibers. The BS characterization indicates that it could be applied as a flame retardant when applied as coating methods using the water-soluble fraction of BS, reducing the burning rate up to 92%. Flammability results are similar for formulations with and without natural fibers, indicating that the natural fibers did not influence the proposed flame retardant. The findings suggest that BS coating is a potential solution to improve the properties of natural fiber-reinforced polymer composites while also promoting waste recycling. This approach produces composites with improved flammability, thermal stability, and mechanical properties, making them suitable for various end applications. Borosilicate residue as flame retardant for natural fiber composites. image
引用
收藏
页数:9
相关论文
共 31 条
  • [1] Improvement on fire retardancy of wood flour/polypropylene composites using various fire retardants
    Arao, Yoshihiko
    Nakamura, Sakae
    Tomita, Yuta
    Takakuwa, Kyouhei
    Umemura, Toshikazu
    Tanaka, Tatsuya
    [J]. POLYMER DEGRADATION AND STABILITY, 2014, 100 : 79 - 85
  • [2] Comparative studies of mechanical and morphological properties of polylactic acid and polypropylene based natural fiber composites
    Bajpai, Pramendra Kumar
    Singh, Inderdeep
    Madaan, Jitendra
    [J]. JOURNAL OF REINFORCED PLASTICS AND COMPOSITES, 2012, 31 (24) : 1712 - 1724
  • [3] Beaumont P. W. R., 1979, FRACT MECH, V1, P211
  • [4] Effects of fiber characteristics on the physical and mechanical properties of wood plastic composites
    Bouafif, Hassine
    Koubaa, Ahmed
    Perre, Patrick
    Cloutier, Alain
    [J]. COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2009, 40 (12) : 1975 - 1981
  • [5] THE IMPACT RESISTANCE OF COMPOSITE-MATERIALS - A REVIEW
    CANTWELL, WJ
    MORTON, J
    [J]. COMPOSITES, 1991, 22 (05): : 347 - 362
  • [6] Effect of boric acid and borax on mechanical, fire and thermal properties of wood flour filled high density polyethylene composites
    Cavdar, Ayfer Donmez
    Mengeloglu, Fatih
    Karakus, Kadir
    [J]. MEASUREMENT, 2015, 60 : 6 - 12
  • [7] RESIDENCE TIME DISTRIBUTION IN SCREW EXTRUDERS
    CHEN, LQ
    PAN, ZQ
    HU, GH
    [J]. AICHE JOURNAL, 1993, 39 (09) : 1455 - 1464
  • [8] FANGLONG Z, 2016, SURF COAT TECH, V294, P90
  • [9] Preparation and thermodynamic characterization of 2CaO•B2O3•H2O nanomaterials with enhanced flame retardant properties
    Geng, Yong-Jie
    Liu, Zhi-Hong
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2017, 522 : 563 - 568
  • [10] Reactive extrusion: Toward nanoblends
    Hu, GH
    Cartier, H
    Plummer, C
    [J]. MACROMOLECULES, 1999, 32 (14) : 4713 - 4718