Rhizopus Hyphae Carbon as Efficient Sulfur Host For Lithium-Sulfur Batteries

被引:0
作者
Zhang, Weiyong [1 ]
Wang, Long [1 ]
Huang, Lei [1 ]
He, Xinping [1 ]
Liang, Xinqi [1 ,2 ,3 ]
Xia, Xinhui [1 ,2 ]
Zhang, Yongqi [3 ]
Cao, Feng [4 ]
Chen, Minghua [5 ]
Wan, Wangjun [6 ]
Wang, Chen [6 ]
Xia, Yang [1 ]
Zhang, Jun [1 ]
Zhang, Wenkui [1 ]
机构
[1] Zhejiang Univ Technol, Coll Mat Sci & Engn, Hangzhou 310014, Peoples R China
[2] Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China
[3] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 611371, Peoples R China
[4] Huzhou Coll, Dept Engn Technol, Huzhou 313000, Peoples R China
[5] Harbin Univ Sci & Technol, Sch Elect & Elect Engn, Key Lab Engn Dielect & Applicat, Minist Educ, Harbin 150080, Peoples R China
[6] Zhejiang Acad Sci & Technol Inspect & Quarantine, Hangzhou 311215, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Biomass; porous carbon; sulfur host; lithium-sulfur battery; ELECTROCHEMICAL PERFORMANCE; CATHODE;
D O I
10.1007/s11664-024-11403-3
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Construction of advanced carbon material is critical for the development of high-performance lithium-sulfur batteries. In this work, we report Rhizopus hyphae biomass carbon (RHBC) as a host material for the sulfur cathode of lithium-sulfur batteries. The porous structure of the RHBC is optimized through hydrothermal activation using KOH solution. The introduction of RHBC into the cathode not only enhances the electronic conductivity of the sulfur cathode, but also substantially improves the capacity of the active materials. Additionally, the RHBC can effectively relieve the volume expansion problem of the sulfur conversion reaction and maintain structural stability, leading to improved lifetime and capacity. Accordingly, the KOH-activated RHBC/S cathode presents initial discharge specific capacity of 748 mAh/g at current density of 0.1 C. Furthermore, the porous structure facilitates rapid transport of electrons and ions, thereby enabling good high-rate performance.
引用
收藏
页码:6605 / 6612
页数:8
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